The aims of this study are to examine (1) the magnitude and spatial variability in the concentration and flux of wet deposited major ions (NO3-N, NH4-N, DOC, PO4-P, Cl, SO4, H+, Ca, Mg, Na, K) across the greater Phoenix metropolitan area, including the developed urban core and outlying desert, and (2) patterns of coarse dry particulate deposition across stated area and provide some minimum estimates on levels of dry deposition of these ions. This study was designed particularly to answer the question: 'To what extent are concentrations and fluxes of these ions enhanced at sites within the urban core relative to undeveloped desert sites upwind and downwind of the city?'.
At the outset, the project featured eight wet-dry collectors positioned spatially so as to form a transect running approximately west-to-east across the central Arizona region from outlying desert to the west, upwind of the prevailing synoptic wind direction, through agriculture to urban core sites, and, finally, to two downwind sites in the desert to the east and northeast. As much as possible, these collectors were co-located with Maricopa County or Arizona Department of Environmental Quality monitoring stations. Monitoring at most sampling locations ran from 1999 through the mid-2000s when sampling was discontinued at several sites. Sampling continued at the Lost Dutchman State Park, also a Desert Fertilization experiment site with a focus on atmospheric deposition, through 2016. Sampling continues at a site on the Arizona State University Tempe campus that was added to the program in 2009.