Data Package Metadata View Summary

2017 seasonal high frequency monitoring of Upper Clark Fork River (Montana, USA) dissolved carbon dioxide, pH, and electrical conductivity

General Information

Data Package:
Local Identifier:	edi.204.8
Title:	2017 seasonal high frequency monitoring of Upper Clark Fork River (Montana, USA) dissolved carbon dioxide, pH, and electrical conductivity
Alternate Identifier:	DOI PLACE HOLDER
Abstract:	These data were collected by the University of Montana and Montana State University to support the Upper Clark Fork River restoration monitoring project supported by the US NSF Long Term Research in Environmental Biology (LTREB) program. The original analytical intent for these data was to assess the response of river metabolic regime to the floodplain restoration via inference of whole-ecosystem metabolism from the daily variation in carbon dioxide concentrations. Data are primarily measurements of dissolved carbon dioxide, pH, electrical conductivity, and temperature in well-mixed river thalweg water. Additional miscellaneous data were collected for quality control. Data are from late in the 2017 field season. Data were collected on the Upper Clark Fork River (USGS HUC 17010201) at the Galen and Racetrack sites northeast of Anaconda, Montana, USA. High frequency carbon dioxide and pH data were collected using field deployments SAMI sensors from Sunburst Sensors (Missoula, Montana, USA). Electrical conductivity data was collected with a HOBO sensor from Onset Computer Corporation (Bourne, Massachusetts, USA).
Purpose:	These data were collected by the University of Montana and Montana State University to support the Upper Clark Fork River restoration monitoring project supported by the US NSF Long Term Research in Environmental Biology (LTREB) program. The original analytical intent for these data was to assess the response of river metabolic regime to the floodplain restoration via inference of whole-ecosystem metabolism from the daily variation in carbon dioxide concentrations.
Publication Date:	2021-07-27

Time Period

Begin:

2017-10-17

End:

2017-11-16

People and Organizations
Contact:	DeGrandpre, Michael D (University of Montana) [ email ]
Creator:	DeGrandpre, Michael D (University of Montana)
Creator:	Beatty, Cory M (University of Montana)
Associate:	Bayrd, Venice (Montana State University, Data curation)
Associate:	Payn, Robert A (Montana State University, Data curation and project PI at MSU)
Associate:	Valett, H Maurice (University of Montana, Project PI at UM)
Associate:	Peipoch, Marc (Stroud Water Research Center, Project co-PI)
Associate:	D'Andrilli, Juliana (Louisiana University Marine Consortium, Project co-PI)

Data Entities
Data Table Name:	Cleaning_Time_Table.csv
Description:	Approximate times when sensors were cleaned. Detailed cleaning times are not available, but sensors were generally cleaned around the time quality assurance samples were taken.
Data Table Name:	Galen_Table_CO2_S5u.csv
Description:	In situ measurements by SAMI CO2 probe ID S5u at Galen site
Data Table Name:	Galen_Table_EC.csv
Description:	In situ measurements by HOBO electrical conductivity probe at Galen site
Data Table Name:	Galen_Table_pH_P87.csv
Description:	In situ measurements by SAMI pH probe ID P87 at Galen site
Data Table Name:	Galen_Table_Pressure.csv
Description:	In situ measurements by HOBO pressure probe at Galen site
Data Table Name:	Galen_Table_QC_Samples.csv
Description:	Measurements and calculations based on river water sampling campaigns for the purpose of quality assurance at Galen site. These data were not used to alter the measurements from the deployed instruments and are provided as information to future users of the dataset.
Data Table Name:	Racetrack_Table_CO2_S53.csv
Description:	In situ measurements by SAMI CO2 probe ID S53 at Racetrack site
Data Table Name:	Racetrack_Table_EC.csv
Description:	In situ measurements by HOBO electrical conductivity probe at Racetrack site
Data Table Name:	Racetrack_Table_pH_S13u.csv
Description:	In situ measurements by SAMI pH probe ID S13u at Racetrack site
Data Table Name:	Racetrack_Table_Pressure.csv
Description:	In situ measurements by HOBO pressure probe at Racetrack site
Data Table Name:	Racetrack_Table_QC_Samples.csv
Description:	Measurements and calculations based on river water sampling campaigns for the purpose of quality assurance at Racetrack site. These data were not used to alter the measurements from the deployed instruments and are provided as information to future users of the dataset.
Other Name:	01_input.zip
Description:	Compressed data pipeline folder containing raw data downloaded from instruments. See methods for details.
Other Name:	02_protocol.zip
Description:	Compressed data pipeline folder containing R markdown and R scripts for processing data and metadata. See methods for details.
Other Name:	03_incremental.zip
Description:	Compressed data pipeline folder containing detailed notes and incremental data associated with generation of the data product. See methods for details.

Detailed Metadata

Data Entities

Data Table


Data:	https://pasta-s.lternet.edu/package/data/eml/edi/204/8/33b335756519bea31341cdcab828fcd4
Name:	Cleaning_Time_Table.csv
Description:	Approximate times when sensors were cleaned. Detailed cleaning times are not available, but sensors were generally cleaned around the time quality assurance samples were taken.
Number of Records:	5
Number of Columns:	1

Table Structure

Object Name:

Cleaning_Time_Table.csv

Size:

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Table Column Descriptions

Column Name:

time

Definition:

Time and date of cleaning using a Gregorian calendar in universal time (UTC). Property: Approximate time. Entity: Sensor cleaning activity. Method: Personal timepiece.

Storage Type:

date

Measurement Type:

dateTime

Measurement Values Domain:

Format	YYYYMMDDThhmmssZ
Precision

Missing Value Code:

Code	NA
Expl	Missing value

Accuracy Report:

Accuracy Assessment:

Coverage:

Methods:

Data Table


Data:	https://pasta-s.lternet.edu/package/data/eml/edi/204/8/08a187436a2e73fb62262c9a6e7604a9
Name:	Galen_Table_CO2_S5u.csv
Description:	In situ measurements by SAMI CO2 probe ID S5u at Galen site
Number of Records:	2799
Number of Columns:	3

Table Structure

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Table Column Descriptions

Column Name:

time

pCO2

temp

Definition:

Time and date of measurement using a Gregorian calendar in universal time (UTC). Property: Time. Entity: Measurement by instrument. Method: Deployed SAMI CO2 probe.

Partial pressure of dissolved CO2 in stream water. Property: Partial pressure of dissolved carbon dioxide. Entity: In-place mixed stream thalweg water. Method: Deployed SAMI CO2 probe.

Temperature of stream water. Property: Temperature. Entity: In-place mixed stream thalweg water. Method: Deployed SAMI CO2 probe.

Storage Type:

date

float

Measurement Type:

dateTime

ratio

Measurement Values Domain:

Format	YYYYMMDDThhmmssZ
Precision

Unit	microatmospheres
Type	real
Min	166.93
Max	786.39

Unit	celsius
Type	real
Min	-3.1122
Max	7.0716

Missing Value Code:

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Accuracy Report:

Accuracy Assessment:

Coverage:

Methods:

Data Table


Data:	https://pasta-s.lternet.edu/package/data/eml/edi/204/8/b6efb0ceed8f00440a7c79f0b65f75c8
Name:	Galen_Table_EC.csv
Description:	In situ measurements by HOBO electrical conductivity probe at Galen site
Number of Records:	8672
Number of Columns:	3

Table Structure

Object Name:

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Size:

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Table Column Descriptions

Column Name:

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temp

Definition:

Time and date of measurement using a Gregorian calendar in universal time (UTC). Property: Time. Entity: Measurement by instrument. Method: Deployed HOBO EC probe.

Temperature corrected electrical conductivity of river water. Property: Electrical conductivity at 25 degrees Celsius. Entity: In-place mixed stream thalweg water. Method: Deployed HOBO EC probe.

River water temperature. Property: Temperature. Entity: In-place mixed stream thalweg water. Method: Deployed HOBO EC probe.

Storage Type:

date

float

Measurement Type:

dateTime

ratio

Measurement Values Domain:

Format	YYYYMMDDThhmmssZ
Precision

Unit	microSiemensPerCentimeter
Type	real
Min	34.1
Max	328

Unit	celsius
Type	real
Min	-0.76
Max	9.02

Missing Value Code:

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Accuracy Report:

Accuracy Assessment:

Coverage:

Methods:

Data Table


Data:	https://pasta-s.lternet.edu/package/data/eml/edi/204/8/9fbf134521c049b3405729bc26815ded
Name:	Galen_Table_pH_P87.csv
Description:	In situ measurements by SAMI pH probe ID P87 at Galen site
Number of Records:	2799
Number of Columns:	3

Table Structure

Object Name:

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Size:

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Table Column Descriptions

Column Name:

time

temp

Definition:

Time and date of measurement using a Gregorian calendar in universal time (UTC). Property: Time. Entity: Measurement by instrument. Method: Deployed SAMI pH probe.

River water pH. Property: Negative log activity of hydrogen ions. Entity: In-place mixed stream thalweg water. Method: Deployed SAMI pH probe.

River water temperature. Property: Temperature. Entity: In-place mixed stream thalweg water. Method: Deployed SAMI pH probe.

Storage Type:

date

float

Measurement Type:

dateTime

ratio

Measurement Values Domain:

Format	YYYYMMDDThhmmssZ
Precision

Unit	dimensionless
Type	real
Min	7.2636
Max	9.5064

Unit	celsius
Type	real
Min	-1.24
Max	9.16

Missing Value Code:

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Accuracy Report:

Accuracy Assessment:

Coverage:

Methods:

Data Table


Data:	https://pasta-s.lternet.edu/package/data/eml/edi/204/8/f24bebdd88fbfab3f3f3a1118f1da25d
Name:	Galen_Table_Pressure.csv
Description:	In situ measurements by HOBO pressure probe at Galen site
Number of Records:	8411
Number of Columns:	3

Table Structure

Object Name:

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Table Column Descriptions

Column Name:

time

pressure

temp

Definition:

Time and date of measurement using a Gregorian calendar in universal time (UTC). Property: Time. Entity: Measurement by instrument. Method: Deployed HOBO pressure probe.

River water pressure. Property: Absolute pressure. Entity: In-place mixed stream thalweg water. Method: Deployed HOBO pressure probe.

River water temperature. Property: Temperature. Entity: In-place mixed stream thalweg water. Method: Deployed HOBO pressure probe.

Storage Type:

date

float

Measurement Type:

dateTime

ratio

Measurement Values Domain:

Format	YYYYMMDDThhmmssZ
Precision

Unit	kilopascals
Type	real
Min	86.765
Max	89.874

Unit	celsius
Type	real
Min	4.1
Max	9.18

Missing Value Code:

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Accuracy Report:

Accuracy Assessment:

Coverage:

Methods:

Data Table


Data:	https://pasta-s.lternet.edu/package/data/eml/edi/204/8/782a7fd9ac9fa5883b7583ba2d618d35
Name:	Galen_Table_QC_Samples.csv
Description:	Measurements and calculations based on river water sampling campaigns for the purpose of quality assurance at Galen site. These data were not used to alter the measurements from the deployed instruments and are provided as information to future users of the dataset.
Number of Records:	6
Number of Columns:	8

Table Structure

Object Name:

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Size:

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Field Delimiter:	,
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Table Column Descriptions

Column Name:

time

alk

temp_P87

pH_P87

temp

pCO2_insitu

pCO2_sample

Definition:

Time and date of sample collection using a Gregorian calendar in universal time (UTC). Property: Time. Entity: Collection of river water sample. Method: Personal timepiece.

pH of a sample of river water adjusted to in situ temperatures. Property: Negative log activity of hydrogen ions. Entity: Sample of unfiltered mixed thalweg stream water. Method: Colorimetry with indicator dye adjusted to in situ temperature.

Total alkalinity of a sample of river water in micromolarity of hydrogen ions neutralized. Property: Total alkalinity. Entity: Sample of unfiltered mixed thalweg stream water. Method: Gran titration.

River water temperature at nearest time to sample collection. Property: Temperature. Entity: In-place mixed stream thalweg water. Method: Deployed SAMI pH sensor at nearest time to sample collection.

River water pH at nearest time to sample collection. Property: Negative log activity of hydrogen ions. Entity: In-place mixed stream thalweg water. Method: Deployed SAMI pH sensor at nearest time to sample collection.

River water temperature at time of sample collection. Property: Temperature. Entity: In-place mixed stream thalweg water. Method: Handheld probe used at time of sample collection.

Calculated partial pressure of CO2 in a sample of river water at in situ temperature. Property: Partial pressure of dissolved carbon dioxide. Entity: Sample of unfiltered mixed thalweg stream water. Method: CO2Sys calculated from alkalinity and pH at in situ temperature.

Calculated partial pressure of CO2 in a sample of river water at sample temperature. Property: Partial pressure of dissolved carbon dioxide. Entity: Sample of unfiltered mixed thalweg stream water. Method: CO2Sys calculated from alkalinity and pH at sample temperature.

Storage Type:

date

float

Measurement Type:

dateTime

ratio

Measurement Values Domain:

Format	YYYYMMDDThhmmssZ
Precision

Unit	dimensionless
Type	real
Min	7.965
Max	8.679

Unit	micromolePerLiter
Type	natural
Min	2577
Max	2853

Unit	celsius
Type	real
Min	-0.06
Max	6.92

Unit	dimensionless
Type	real
Min	8.128
Max	8.2391

Unit	celsius
Type	real
Min	0.2
Max	6.82

Unit	microatmospheres
Type	real
Min	277.2
Max	1469.2

Unit	microatmospheres
Type	real
Min	769.8
Max	1006.5

Missing Value Code:

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Expl	Missing value

Code	NA
Expl	Missing value

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Expl	Missing value

Code	NA
Expl	Missing value

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Expl	Missing value

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Accuracy Report:

Accuracy Assessment:

Coverage:

Methods:

Data Table


Data:	https://pasta-s.lternet.edu/package/data/eml/edi/204/8/3d6c793b6ce74237664f31f738832642
Name:	Racetrack_Table_CO2_S53.csv
Description:	In situ measurements by SAMI CO2 probe ID S53 at Racetrack site
Number of Records:	2794
Number of Columns:	3

Table Structure

Object Name:

Racetrack_Table_CO2_S53.csv

Size:

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Authentication:

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Orientation:

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Simple Delimited:

Field Delimiter:	,
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Table Column Descriptions

Column Name:

time

pCO2

temp

Definition:

Time and date of measurement using a Gregorian calendar in universal time (UTC). Property: Time. Entity: Measurement by instrument. Method: Deployed SAMI CO2 probe.

Partial pressure of dissolved CO2 in stream water. Property: Partial pressure of dissolved carbon dioxide. Entity: In-place mixed stream thalweg water. Method: Deployed SAMI CO2 probe.

Temperature of stream water. Property: Temperature. Entity: In-place mixed stream thalweg water. Method: Deployed SAMI CO2 probe.

Storage Type:

date

float

Measurement Type:

dateTime

ratio

Measurement Values Domain:

Format	YYYYMMDDThhmmssZ
Precision

Unit	microatmospheres
Type	real
Min	68.894
Max	1143.9

Unit	celsius
Type	real
Min	-0.08473
Max	9.2675

Missing Value Code:

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Accuracy Report:

Accuracy Assessment:

Coverage:

Methods:

Data Table


Data:	https://pasta-s.lternet.edu/package/data/eml/edi/204/8/b1d29ead20ef0a3b4a33ee7898790755
Name:	Racetrack_Table_EC.csv
Description:	In situ measurements by HOBO electrical conductivity probe at Racetrack site
Number of Records:	8660
Number of Columns:	3

Table Structure

Object Name:

Racetrack_Table_EC.csv

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Table Column Descriptions

Column Name:

time

temp

Definition:

Time and date of measurement using a Gregorian calendar in universal time (UTC). Property: Time. Entity: Measurement by instrument. Method: Deployed HOBO EC probe.

Temperature corrected electrical conductivity of river water. Property: Electrical conductivity at 25 degrees Celsius. Entity: In-place mixed stream thalweg water. Method: Deployed HOBO EC probe.

River water temperature. Property: Temperature. Entity: In-place mixed stream thalweg water. Method: Deployed HOBO EC probe.

Storage Type:

date

float

Measurement Type:

dateTime

ratio

Measurement Values Domain:

Format	YYYYMMDDThhmmssZ
Precision

Unit	microSiemensPerCentimeter
Type	real
Min	99.6
Max	334.8

Unit	celsius
Type	real
Min	-0.26
Max	9.36

Missing Value Code:

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Accuracy Report:

Accuracy Assessment:

Coverage:

Methods:

Data Table


Data:	https://pasta-s.lternet.edu/package/data/eml/edi/204/8/67ceff9a9d79d22f67524dfb999debf3
Name:	Racetrack_Table_pH_S13u.csv
Description:	In situ measurements by SAMI pH probe ID S13u at Racetrack site
Number of Records:	2793
Number of Columns:	3

Table Structure

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Table Column Descriptions

Column Name:

time

temp

Definition:

Time and date of measurement using a Gregorian calendar in universal time (UTC). Property: Time. Entity: Measurement by instrument. Method: Deployed SAMI pH probe.

River water pH. Property: Negative log activity of hydrogen ions. Entity: In-place mixed stream thalweg water. Method: Deployed SAMI pH probe.

River water temperature. Property: Temperature. Entity: In-place mixed stream thalweg water. Method: Deployed SAMI pH probe.

Storage Type:

date

float

Measurement Type:

dateTime

ratio

Measurement Values Domain:

Format	YYYYMMDDThhmmssZ
Precision

Unit	dimensionless
Type	real
Min	8.2383
Max	9.5511

Unit	celsius
Type	real
Min	-0.17
Max	9.2

Missing Value Code:

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Accuracy Report:

Accuracy Assessment:

Coverage:

Methods:

Data Table


Data:	https://pasta-s.lternet.edu/package/data/eml/edi/204/8/372f3253d12d1c3c77fb873590ee9f8b
Name:	Racetrack_Table_Pressure.csv
Description:	In situ measurements by HOBO pressure probe at Racetrack site
Number of Records:	8342
Number of Columns:	3

Table Structure

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Table Column Descriptions

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pressure

temp

Definition:

Time and date of measurement using a Gregorian calendar in universal time (UTC). Property: Time. Entity: Measurement by instrument. Method: Deployed HOBO pressure probe.

River water pressure. Property: Absolute pressure. Entity: In-place mixed stream thalweg water. Method: Deployed HOBO pressure probe.

River water temperature. Property: Temperature. Entity: In-place mixed stream thalweg water. Method: Deployed HOBO pressure probe.

Storage Type:

date

float

Measurement Type:

dateTime

ratio

Measurement Values Domain:

Format	YYYYMMDDThhmmssZ
Precision

Unit	kilopascals
Type	real
Min	85.378
Max	89.513

Unit	celsius
Type	real
Min	-0.1
Max	9.28

Missing Value Code:

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Accuracy Report:

Accuracy Assessment:

Coverage:

Methods:

Data Table


Data:	https://pasta-s.lternet.edu/package/data/eml/edi/204/8/ecb6a28f600cefa3e6b7b560562174ae
Name:	Racetrack_Table_QC_Samples.csv
Description:	Measurements and calculations based on river water sampling campaigns for the purpose of quality assurance at Racetrack site. These data were not used to alter the measurements from the deployed instruments and are provided as information to future users of the dataset.
Number of Records:	6
Number of Columns:	7

Table Structure

Object Name:

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Table Column Descriptions

Column Name:

time

alk

temp_P87

temp

pCO2_insitu

temp_S53u

Definition:

Time and date of sample collection using a Gregorian calendar in universal time (UTC). Property: Time. Entity: Collection of river water sample. Method: Personal timepiece.

Total alkalinity of a sample of river water in micromolarity of hydrogen ions neutralized. Property: Total alkalinity. Entity: Sample of unfiltered mixed thalweg stream water. Method: Gran titration.

River water temperature at nearest time to sample collection. Property: Temperature. Entity: In-place mixed stream thalweg water. Method: Deployed SAMI pH sensor at nearest time to sample collection.

River water temperature at time of sample collection. Property: Temperature. Entity: In-place mixed stream thalweg water. Method: Handheld probe used at time of sample collection.

River water temperature at nearest time to sample collection. Property: Temperature. Entity: In-place mixed stream thalweg water. Method: Deployed SAMI CO2 sensor at nearest time to sample collection.

Storage Type:

date

float

Measurement Type:

dateTime

ratio

Measurement Values Domain:

Format	YYYYMMDDThhmmssZ
Precision

Unit	dimensionless
Type	real
Min	8.055
Max	8.688

Unit	micromolePerLiter
Type	natural
Min	2623
Max	2984

Unit	celsius
Type	real
Min	-0.04
Max	6.83

Unit	celsius
Type	real
Min	0.4
Max	7

Unit	microatmospheres
Type	real
Min	275
Max	1304.2

Unit	celsius
Type	real
Min	5.52
Max	5.52

Missing Value Code:

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Code	NA
Expl	Missing value

Accuracy Report:

Accuracy Assessment:

Coverage:

Methods:

Non-Categorized Data Resource

Name:

01_input.zip

Entity Type:

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Compressed data pipeline folder containing raw data downloaded from instruments. See methods for details.

Physical Structure Description:

Object Name:

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1439466 bytes

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Compressed data pipeline folder containing detailed notes and incremental data associated with generation of the data product. See methods for details.

Physical Structure Description:

Object Name:

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3233257 bytes

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application/zip

Data:

https://pasta-s.lternet.edu/package/data/eml/edi/204/8/e269ff6c46d3c6c4aba7cbee117b8289

Data Package Usage Rights

This data package is released to the "public domain" under Creative Commons CC0 1.0 "No Rights Reserved" (see: https://creativecommons.org/publicdomain/zero/1.0/). It is considered professional etiquette to provide attribution of the original work if this data package is shared in whole or by individual components. A generic citation is provided for this data package on the website https://portal.edirepository.org (herein "website") in the summary metadata page. Communication (and collaboration) with the creators of this data package is recommended to prevent duplicate research or publication. This data package (and its components) is made available "as is" and with no warranty of accuracy or fitness for use. The creators of this data package and the website shall not be liable for any damages resulting from misinterpretation or misuse of the data package or its components. Periodic updates of this data package may be available from the website. Thank you.

Keywords

By Thesaurus:
(No thesaurus)	Upper Clark Fork River restoration, NSF DEB LTREB 1655197, Montana, Northwestern United States, Northwestern Forested Mountains Ecoregion
NALT	river water, pH, dissolved carbon dioxide
LTER Controlled Vocabulary	electrical conductivity

Methods and Protocols

These methods, instrumentation and/or protocols apply to all data in this dataset:

Methods and protocols used in the collection of this data package

Description:

## 1. Measurement methods Each description below is cross-referenced with the brief methods caption provided in the descriptions of the table columns. _Deployed SAMI CO2 probe_: A Submersible Autonomous Moored Instrument (SAMI) CO2 probe (Sunburst Sensors, Missoula, Montana, USA) was deployed directly in the channel thalweg and measured the partial pressure of dissolved CO2 in river water. The pH of the indicator fluid measured by colorimetric absorbance can then be calibrated to the influence of dissolved carbon dioxide gas on the buffering system of the indicator. Calibrations were carried out in the DeGrandpre lab at University of Montana. The probe also records the water temperature and time of measurements. _Deployed SAMI pH probe_: A Submersible Autonomous Moored Instrument (SAMI) pH probe (Sunburst Sensors, Missoula, Montana, USA) was deployed directly in the channel thalweg and measured pH in the river water. Samples of river water are automatically pumped into the SAMI and are passively mixed with indicator dye. A spectrophotometric measurement of the mixture provides a value for pH. The probe also records the water temperature and time of measurements. _Deployed HOBO EC probe_: An Onset Hobo electrical conductivity probe (Onset Computer Corporation, Bourne, Massachusetts, USA) was deployed directly in the channel thalweg and measured the temperature-corrected electrical conductivity in river water. The electrical conductivity is measured by applying a voltage across leads with a specific geometry of connection with river water and measuring the resistance between those leads to conducting an electrical current. The probe also records the water temperature and time of measurements. The software from the manufacturer of the probe (Hobo Onset) provides a post-processor that performs the temperature-correction of the conductivity to 25 degrees Celsius. The factory calibration was used on the instrument. _Deployed HOBO pressure probe_: An Onset Hobo pressure transducer (Onset Computer Corporation, Bourne, Massachusetts, USA) was deployed with the SAMI CO2 probe to track the relative variation in river depth during the deployment. The pressure transducers derives absolute pressure by measuring the deformation of a ceramic diaphragm. The probe also records the water temperature and time of measurements. The following methods apply to data collected for quality assurance. Sensor deployment data have not been altered based on these measurements, and they are provided for information to future users. _Colorimetry with indicator dye_: For quality assurance purposes, pH of discrete river water samples was measured in a laboratory setting following the procedures in Lai et al. (2016). Briefly, indicator dyes were added to river samples stored in a 10-cm cylindrical optical cell. Values of pH for the samples were obtained by monitoring the spectrum of the dye-sample mixture via a Cary 300 spectrophotometer (Varian, Inc.). Measurements are routinely performed at ~20 degrees Celsius and corrected to in situ temperature (i.e. temperature when samples were taken) using the CO2Sys Excel spreadsheet model for the inorganic carbon system (Pierrot et al., 2006). _Gran titration_: Alkalinity samples were measured by acidimetric open-cell titration (Gran 1952). Alkalinity is inferred from non-linear regression analysis from a titration curve between pH values of 3.5 and 3.0. Results of Gran titration are presented as molarity and can be interpreted as the molarity of hydrogen ions neutralized by proton accepting compounds dissolved in the water. _CO2Sys calculated from alkalinity and pH_: The CO2Sys model (Pierrot et al., 2006) was used to calculate the partial pressure of carbon dioxide in sampled river water from the measured alkalinity and pH. Partial pressure of carbon dioxide was calculated for both bottle temperature at time of lab analysis and in situ river water temperature at the time of sample collection. ## 2. Data processing methods This data product is designed to provide the provenance of final tables in a pipeline format, to the degree that provenance is available. Raw data files from instruments and manufacturer software are available in the 01\_input.zip file. The coding used to process the data is available in the 02\_protocol.zip file. In this case, final processing was carried out with R scripts and R markdown files. Incremental files created for the purpose of data processing are available in the 03\_incremental.zip file. Ready-to-use analytical data are available at the data package's root level (on the dataset landing page under the "Resources" section) and are described in the full metadata. ### 2.1. Contents of 01\_input.zip * _003\_HoboCond\_20200212\_2017-OCT.hobo_ - Binary file for In Situ Hobo electrical conductivity sensor serial number 20200212 * _2021 Site Table.xlsx_ - Microsoft Excel file with authoritative project site list at the time of publication of these data. * _Cond\_20200211.csv_ - Comma delimited export of data for In Situ Hobo electrical conductivity sensor serial number 20200211 * _Cond\_20200211.hobo_ - Binary file for In Situ Hobo electrical conductivity sensor serial number 20200211 * _Cond\_20200212.csv_ - Comma delimited export of data for In Situ Hobo electrical conductivity sensor serial number 20200212 * _Depth\_20183501\_111517.csv_ - Comma delimited export of data for In Situ Hobo pressure sensor serial number 20183501 * _Depth\_20183502\_111517.csv_ - Comma delimited export of data for In Situ Hobo pressure sensor serial number 20183502 * _intellectual\_rights.txt_ - A text file sourcing the license for data use. * _people.xlsx_ - Excel file with tabular data on people associated with the project used for metadata generation. * _SAMI\_P87\_151117.txt_ - Raw file for SAMI pH sensor serial number P87 * _SAMI\_S5u\_151117.txt_ - Raw file for SAMI CO2 sensor serial number S5u * _SAMI\_S13u\_151117.txt_ - Raw file for SAMI pH sensor serial number S13u * _SAMI\_S53u\_151117.txt_ - Raw file for SAMI CO2 sensor serial number S53u ### 2.2. Contents of 02\_protocol.zip R code in the protocol depends on R packages: tidyr, readtext, knitr, readxl, EMLassemblyline, and xml2. Code also makes system calls to the zip command using arguments compatible with Info-Zip implementation 3.0, which appear to be mostly consistent with linux zip arguments. * _meta/_ - Directory with narrative metadata elements incorporated into metadata summary and EML * _abstract.md_ - A markdown file sourcing the data abstract. * _methods.md_ - A markdown file sourcing the description of methods. * _purpose.txt_ - A text file sourcing the description of purpose. * _supplemental/_ - Directory with supplemental protocol provenance data * _CO2sys\_Freshwater\_2020.xlsm_ - Version 2.1 (18 September 2012) of the CO2Sys spreadsheet (Pierrot et al., 2006) used to adjust the pH measured in the lab to ambient river temperatures at the time of sampling. (Data are not in this spreadsheet. It is provided for convenience.) * _.RProfile_ - An R profile file with R code that establishes the appropriate working directory for the R project used to generate this data product. * _00\_deployment\_notes.docx_ - Microsoft Word document for generating the deployment notes PDF file * _01\_cleaning\_dates\_table.R_ - R script that generates the table and metadata for the cleaning dates * _02\_galen\_tables.Rmd_ - R markdown defining the quality assurance visualizations, tables, and metadata for Galen site data * _02\_galen\_tables\_compile.R_ - R script that compiles the Galen site R markdown to a PDF document (03\_incremental.zip - Notes\_Galen\_Processing.pdf) * _03\_racetrack\_tables.Rmd_ - R markdown defining the quality assurance visualizations, tables, and metadata for Racetrack site data * _03\_racetrack\_tables\_compile.R_ - R script that compiles the Racetrack site R markdown to a PDF document (03\_incremental.zip - Notes\_Racetrack\_Processing.pdf) * _10\_metadata.Rmd_ - R markdown defining the generation of the metadata file and the EML file based on EDI EML assembly line. * _10\_metadata\_compile.R_ - R script that compiles the metadata R markdown to an HTML document (metadata.html) and an EML file (eml.xml). * _99\_runall.R_ - Convenience R script for fully regenerating the data product. * _base.R_ - Shared utility R code used in R markdown files. * _RStudioProject.Rproj_ - An RStudio project file provided for convenience in working with the code generating this data product with the appropriate working directory. ### 2.3. Contents of 03\_incremental.zip * _2017\_UCFR\_Sensor\_Deployment\_Data\_Stackplot\_pCO2\_pH\_T.pdf_ - A visualization generated for data quality assurance purposes. The three plots include time on the abscissa with pH, Temperature, and pCO2 on separate ordinate axes. * _Data\_2017\_LTREB\_Bottle\_Data\_For\_QA.xlsx_ - Microsoft Excel file with the original quality assurance data from grab samples compiled by Cory Beatty * _Data\_2017\_UCFR\_Sensor\_Deployment\_QA.xlsx_ - Microsoft Excel file with the original sensor data compiled by Cory Beatty * _metadata\_summary.html_ - Summary of metadata and the process of archiving the workflow pipeline and compiling the associated metadata into EML * _Notes\_Deployment.pdf_ - Original deployment notes compiled by Cory Beatty * _Notes\_Galen\_Processing.html_ - Notes on generating data tables for Galen site * _Notes\_Racetrack\_Processing.html_ - Notes on generating data tables for Racetrack site ## 3. References: Gran, G. 1952. Determination of the equivalence point in potentiometric titrations. Part II. Analyst 77: 661-671. doi: 10.1039/AN9527700661 Lai C.-Z., M. D. DeGrandpre, B. D. Wasser, T. A. Brandon, D. S. Clucas, E. J. Jaqueth, Z. D. Benson, C. M. Beatty, and R. S. Spauldin. 2016. Spectrophotometric measurement of freshwater pH with purified meta-cresol purple and phenol red. Limnology and Oceanography: Methods 14(12) 864-873. doi: 10.1002/lom3.10137. Pierrot, D. E. Lewis,and D. W. R. Wallace. 2006. MS Excel Program Developed for CO2 System Calculations. ORNL/CDIAC-105a. Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, U.S. Department of Energy, Oak Ridge, Tennessee. doi: 10.3334/CDIAC/otg.CO2SYS\_XLS\_CDIAC105a ## 4. Data product development history * 2021 July 27: Minor corrections, added CO2Sys, updated EDI staging * 2021 July 22: Updated formatting in methods markdown * 2021 July 17: Added this dev history log and updated to generate EML

People and Organizations

Publishers:

Organization:

Environmental Data Initiative

Email Address:

info@environmentaldatainitiative.org

Web Address:

https://environmentaldatainitiative.org

Creators:

Individual:

Michael D DeGrandpre

Organization:

University of Montana

Email Address:

michael.degrandpre@mso.umt.edu

Id:

https://orcid.org/0000-0003-1969-6709

Individual:

Cory M Beatty

Organization:

University of Montana

Email Address:

cory.beatty@mso.umt.edu

Id:

https://orcid.org/0000-0001-7868-2257

Contacts:

Individual:

Michael D DeGrandpre

Organization:

University of Montana

Email Address:

michael.degrandpre@mso.umt.edu

Id:

https://orcid.org/0000-0003-1969-6709

Associated Parties:

Individual:

Venice Bayrd

Organization:

Montana State University

Email Address:

venice.bayrd@montana.edu

Id:

https://orcid.org/0000-0002-5814-9380

Role:

Data curation

Individual:

Robert A Payn

Organization:

Montana State University

Email Address:

rpayn@montana.edu

Id:

https://orcid.org/0000-0001-8421-525X

Role:

Data curation and project PI at MSU

Individual:

H Maurice Valett

Organization:

University of Montana

Email Address:

Maury.Valett@mso.umt.edu

Id:

https://orcid.org/0000-0001-7146-6420

Role:

Project PI at UM

Individual:

Marc Peipoch

Organization:

Stroud Water Research Center

Email Address:

mpeipoch@stroudcenter.org

Id:

https://orcid.org/0000-0002-5943-831X

Role:

Project co-PI

Individual:

Juliana D'Andrilli

Organization:

Louisiana University Marine Consortium

Email Address:

jdandrilli@lumcon.edu

Id:

https://orcid.org/0000-0002-3352-2564

Role:

Project co-PI

Temporal, Geographic and Taxonomic Coverage

Temporal, Geographic and/or Taxonomic information that applies to all data in this dataset:

Time Period

Begin:

2017-10-17

End:

2017-11-16

Sampling Site:

Description:

Site ID 003, restoration project reach A: bridge on Galen Road (site name: Galen)

Site Coordinates:

Longitude (degree):

-112.753194444444

Latitude (degree):

46.2373

Sampling Site:

Description:

Site ID 004, restoration project reach A: bridge on corner of W River Road and Gembeck Road, upstream of of Racetrack exit (site name: Racetrack)

Site Coordinates:

Longitude (degree):

-112.744577777778

Latitude (degree):

46.2654055555556

Project

Parent Project Information:

Title:

LTREB: Collaborative research - River ecosystem responses to floodplain restoration

Personnel:

Individual:

H Maurice Valett

Organization:

University of Montana

Email Address:

Maury.Valett@mso.umt.edu

Id:

https://orcid.org/0000-0001-7146-6420

Role:

Principal Investigator

Funding:

US National Science Foundation 1655197

Related Project:

Title:

LTREB: Collaborative research - River ecosystem responses to floodplain restoration

Personnel:

Individual:

Robert A Payn

Organization:

Montana State University

Email Address:

rpayn@montana.edu

Id:

https://orcid.org/0000-0001-8421-525X

Role:

Principal Investigator

Funding:

US National Science Foundation 1655198

Maintenance

Maintenance:

Description:	Completed: Updates to these data are not expected
Frequency:

Other Metadata

Additional Metadata

additionalMetadata
        |___text '\n    '
        |___element 'metadata'
        |     |___text '\n      '
        |     |___element 'unitList'
        |     |     |___text '\n        '
        |     |     |___element 'unit'
        |     |     |     |  \___attribute 'id' = 'microatmospheres'
        |     |     |     |  \___attribute 'multiplierToSI' = '0.101325'
        |     |     |     |  \___attribute 'name' = 'microatmospheres'
        |     |     |     |  \___attribute 'parentSI' = 'pascal'
        |     |     |     |  \___attribute 'unitType' = 'pressure'
        |     |     |     |___text '\n          '
        |     |     |     |___element 'description'
        |     |     |     |     |___text 'microatmospheres'
        |     |     |     |___text '\n        '
        |     |     |___text '\n        '
        |     |     |___element 'unit'
        |     |     |     |  \___attribute 'id' = 'microSiemensPerCentimeter'
        |     |     |     |  \___attribute 'multiplierToSI' = '0.00000001'
        |     |     |     |  \___attribute 'name' = 'microSiemensPerCentimeter'
        |     |     |     |  \___attribute 'parentSI' = 'siemensPerMeter'
        |     |     |     |  \___attribute 'unitType' = 'conductance'
        |     |     |     |___text '\n          '
        |     |     |     |___element 'description'
        |     |     |     |     |___text 'microSiemens per centimeter'
        |     |     |     |___text '\n        '
        |     |     |___text '\n        '
        |     |     |___element 'unit'
        |     |     |     |  \___attribute 'id' = 'kilopascals'
        |     |     |     |  \___attribute 'multiplierToSI' = '1000'
        |     |     |     |  \___attribute 'name' = 'kilopascals'
        |     |     |     |  \___attribute 'parentSI' = 'pascals'
        |     |     |     |  \___attribute 'unitType' = 'pressure'
        |     |     |     |___text '\n          '
        |     |     |     |___element 'description'
        |     |     |     |     |___text 'kilopascals'
        |     |     |     |___text '\n        '
        |     |     |___text '\n        '
        |     |     |___element 'unit'
        |     |     |     |  \___attribute 'id' = 'micromolePerLiter'
        |     |     |     |  \___attribute 'multiplierToSI' = '0.000001'
        |     |     |     |  \___attribute 'name' = 'micromolePerLiter'
        |     |     |     |  \___attribute 'parentSI' = 'molePerLiter'
        |     |     |     |  \___attribute 'unitType' = 'concentration'
        |     |     |     |___text '\n          '
        |     |     |     |___element 'description'
        |     |     |     |     |___text 'micromole per liter'
        |     |     |     |___text '\n        '
        |     |     |___text '\n      '
        |     |___text '\n    '
        |___text '\n  '

Copyright 2024 Environmental Data Initiative. This material is based upon work supported by the National Science Foundation under grants #2223103 and #2223104. Any opinions, findings, conclusions, or recommendations expressed in the material are those of the author(s) and do not necessarily reflect the views of the National Science Foundation. Please contact us with questions, comments, or for technical assistance regarding this web site or the Environmental Data Initiative. Please read our privacy policy to know what information we collect about you and to understand your privacy rights.

EDI is a collaboration between the University of New Mexico and the University of Wisconsin – Madison, Center for Limnology:

Data Package Metadata View Summary

2017 seasonal high frequency monitoring of Upper Clark Fork River (Montana, USA) dissolved carbon dioxide, pH, and electrical conductivity

Data Entities

Data Table

Data Table

Data Table

Data Table

Data Table

Data Table

Data Table

Data Table

Data Table

Data Table

Data Table

Non-Categorized Data Resource

Non-Categorized Data Resource

Non-Categorized Data Resource

Data Package Usage Rights

Keywords

Methods and Protocols

These methods, instrumentation and/or protocols apply to all data in this dataset:

People and Organizations

Temporal, Geographic and Taxonomic Coverage

Project

Parent Project Information:

Maintenance

Additional Metadata

Recently Added

Recently Updated

Data Package Metadata View Summary

2017 seasonal high frequency monitoring of Upper Clark Fork River (Montana, USA) dissolved carbon dioxide, pH, and electrical conductivity

+/- Data Entities

Data Table

Data Table

Data Table

Data Table

Data Table

Data Table

Data Table

Data Table

Data Table

Data Table

Data Table

Non-Categorized Data Resource

Non-Categorized Data Resource

Non-Categorized Data Resource

+/- Data Package Usage Rights

+/- Keywords

+/- Methods and Protocols

These methods, instrumentation and/or protocols apply to all data in this dataset:

+/- People and Organizations

+/- Temporal, Geographic and Taxonomic Coverage

+/- Project

Parent Project Information:

+/- Maintenance

+/- Additional Metadata

Data Entities

Data Package Usage Rights

Keywords

Methods and Protocols

People and Organizations

Temporal, Geographic and Taxonomic Coverage

Project

Maintenance

Additional Metadata