Water samples are collected from the Des Moines River monthly (November
through February) or bi-weekly (March through October) to monitor water
quality of the river above and below two major reservoirs constructed by the
US Army Corps of Engineers (Saylorville and Red Rock Reservoirs).
The water samples are kept on ice until they are returned to the lab for
analysis. For nitrate analysis, the samples are filtered with a glass fiber
filter (nominal pore size = 0.45 micrometer), preserved with concentrated
sulfuric acid, and analyzed using the cadmium reduction method (EPA 353.2
v2) on a Seal AQ2 Discrete Analyzer.
Duplicate samples are taken at a rate of 10% in the field. In the lab,
nitrate sample analysis is duplicated at a rate of 100% and must be within
20% of each other. Sample are spiked at a rate of 10% and the spike recovery
range is +/- 20%. Two quality control standards are analyzed every 7-10
samples in the analysis run with an acceptable range of +/-10% the expected
concentration.