Definition: | sampling location (for internal reference) | watershed name | ISCO autosampler container number | normal vs. duplicate samples | year | month | day sampled | hour sampled | seasons, determined on a three-month basis | running day for a year | running day of project | If flagged with '< DL' then data are below the detection limit (0.5 ueq/L). If flagged with '< RL' then data are below the reporting limit (2.5 ueq/L) and should be used with caution. | Calcium, determined by: - Atomic Absorption Spectrophotometry (AAS) with N2O-acetylene flame (1998 and prior) - Inductively Coupled Atomic Emission Spectroscopy (ICP) from 1999-2003 - Ion Chromatography (2004 forward) | If flagged with '< DL' then data are below the detection limit (0.8 ueq/L). If flagged with '< RL' then data are below the reporting limit (4.1 ueq/L) and should be used with caution. | Magnesium, determined by: - Atomic Absorption Spectrophotometry (AAS) with N2O-acetylene flame (1998 and prior) - Inductively Coupled Atomic Emission Spectroscopy (ICP) from 1999-2003 - Ion Chromatography (2004 forward) | If flagged with '< DL' then data are below the detection limit (0.3 ueq/L). If flagged with '< RL' then data are below the reporting limit (1.3 ueq/L) and should be used with caution. | Potassium, determined by: - Atomic Absorption Spectrophotometry (AAS) with N2O-acetylene flame (1998 and prior) - Inductively Coupled Atomic Emission Spectroscopy (ICP) from 1999-2003 - Ion Chromatography (2004 forward) | If flagged with '< DL' then data are below the detection limit (0.4 ueq/L). If flagged with '< RL' then data are below the reporting limit (2.2 ueq/L) and should be used with caution. | Sodium, determined by: - Atomic Absorption Spectrophotometry (AAS) with N2O-acetylene flame (1998 and prior) - Inductively Coupled Atomic Emission Spectroscopy (ICP) from 1999-2003 - Ion Chromatography (2004 forward) | Chloride, determined by ion chromatography | If flagged with '< DL' then data are below the detection limit (0.5 ueq/L). If flagged with '< RL' then data are below the reporting limit (2 ueq/L) and should be used with caution. | Sulfate, determined by ion chromatography | Nitrate flag: If flagged with '< DL' then data are below the detection limit (0.1 ueq/L). If flagged with '< RL' then data are below the reporting limit (1.0 ueq/L) and should be used with caution. | Nitrate, determined by ion chromatography Detection Limit: 0.1 ueq/L. Reporting Limit: 1.0 ueq/L. | Ammonium flag: If flagged with '< DL' then data are below the detection limit (0.05 mg/L). If flagged with '< RL' then data are below the reporting limit (0.1 mg/L) and should be used with caution. | Ammonium, determined by: - Autoanalyzer (2003 and prior) - Ion Chromatography (2004 forward) | Total dissolved aluminum, determined by: Atomic absorption spectroscopy with graphite furnace (1998 and prior), Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) 1999-2015, ICP-Mass Spectrometry (ICP-MS) from 2016 | Organic aluminum, determined after filtration through exchange resin by: Atomic absorption spectroscopy with graphite furnace (1998 and prior), Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) 1999-2015, ICP-Mass Spectrometry (ICP-MS) from 2016 | Dissolved organic carbon flag, if flagged with '< DL' then data are below the detection limit (0.1 mg/L). If flagged with '< RL' then data are below the reporting limit (0.5 mg/L) and should be used with caution. | Dissolved organic carbon, determined by infrared carbon analyzer, persulfate oxidation | Dissolved inorganic carbon flag, if flagged with '< DL' then data are below the detection limit (0.1 mg/L). If flagged with '< RL' then data are below the reporting limit (0.5 mg/L) and should be used with caution. | Dissolved organic carbon, determined by infrared carbon analyzer, persulfate oxidation | Total nitrogen flag: If flagged with '< DL' then data are below the detection limit (0.05 mg/L). If flagged with '< RL' then data are below the reporting limit (0.1 mg/L) and should be used with caution. | Total nitrogen, determined by automated colorimetry | Total phosphorus flag, if flagged with '< DL' then data are below the detection limit (0.5 ug/L). If flagged with '< RL' then data are below the reporting limit (1.0 ug/L) and should be used with caution. | Total phosphorus, determined by manual colorimetry | Silica flag: If flagged with '< DL' then data are below the detection limit (0.1mg/L). If flagged with '< RL' then data are below the reporting limit (0.5 mg/L) and should be used with caution. | Silica, determined by autoanalyzer | Acid-neutralizing capacity, determined by Gran titration. ANC is not measured on most samples, when pH is < 5.5 | Measured conductivity, determined with a Wheatstone bridge | stream discharge | hydrogen ions | bicarbonate | closed cell pH, determined by electrode in sealed environment | Air-equilibrated pH, determined by electrode, with standard air (300 ppm CO2) bubbled in | Apparent color flag, If flagged with '< RL' then data are below the reporting limit (5 PCU) and should be used with caution. | Apparent color, unfiltered sample, determined by 475.5 nm spectrophotometer until 2002 and after June 2004, and by color wheel 2003-June 2004. | True color flag, If flagged with '< RL' then data are below the reporting limit (5 PCU) and should be used with caution. | True Color, determined by Hach Pt-Co color kit or Bausch & Lomb Spectronic 70 spectrophotometer | Notes when analytical holding times were exceeded or when missing values were substituted with calculated alternatives (rarely). Data users should determine applicability of data for these values. |
Measurement Values Domain: | Definition | sampling location (for internal reference) |
| Allowed Values and DefinitionsEnumerated Domain | | Code Definition | Code | EB | Definition | East Bear | Source | |
| Code Definition | Code | WB | Definition | West Bear | Source | |
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| Definition | ISCO autosampler container number |
| Allowed Values and DefinitionsEnumerated Domain | | Code Definition | Code | REG | Definition | regular sample | Source | |
| Code Definition | Code | DUP | Definition | field duplicate | Source | |
| Code Definition | Code | REP | Definition | laboratory analytical replicate | Source | |
| Code Definition | Code | ISCO | Definition | autosampler | Source | |
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|
| Unit | nominalYear | Type | natural | Min | 1986 | Max | 2016 |
| Unit | nominalMonth | Type | natural | Min | 1 | Max | 12 |
| Unit | nominalDay | Type | whole | Min | 0 | Max | 31 |
| Unit | nominalHour | Type | whole | Min | 0 | Max | 24 |
| Allowed Values and DefinitionsEnumerated Domain | | Code Definition | Code | WINTER | Definition | DJF | Source | |
| Code Definition | Code | SPRING | Definition | MAM | Source | |
| Code Definition | Code | SUMMER | Definition | JJA | Source | |
| Code Definition | Code | FALL | Definition | SON | Source | |
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| Unit | dimensionless | Type | real | Min | 1.67 | Max | 366.7 |
| Unit | dimensionless | Type | real | Min | 274 | Max | 11320.42 |
| Definition | If flagged with '< DL' then data are below the detection limit (0.5 ueq/L). If flagged with '< RL' then data are below the reporting limit (2.5 ueq/L) and should be used with caution. |
| Unit | microEquivalentsPerLiter | Type | natural | Min | 27 | Max | 159 |
| Allowed Values and DefinitionsEnumerated Domain | | Code Definition | Code | RL | Definition | below the reporting limit | Source | |
|
|
| Unit | microEquivalentsPerLiter | Type | natural | Min | 3 | Max | 58 |
| Allowed Values and DefinitionsEnumerated Domain | | Code Definition | Code | RL | Definition | below the reporting limit | Source | |
|
|
| Unit | microEquivalentsPerLiter | Type | real | Min | 0.6 | Max | 44 |
| Definition | If flagged with '< DL' then data are below the detection limit (0.4 ueq/L). If flagged with '< RL' then data are below the reporting limit (2.2 ueq/L) and should be used with caution. |
| Unit | microEquivalentsPerLiter | Type | natural | Min | 30 | Max | 155 |
| Unit | microEquivalentsPerLiter | Type | natural | Min | 7 | Max | 210 |
| Definition | If flagged with '< DL' then data are below the detection limit (0.5 ueq/L). If flagged with '< RL' then data are below the reporting limit (2 ueq/L) and should be used with caution. |
| Unit | microEquivalentsPerLiter | Type | natural | Min | 32 | Max | 247 |
| Allowed Values and DefinitionsEnumerated Domain | | Code Definition | Code | DL | Definition | below the detection limit | Source | |
| Code Definition | Code | RL | Definition | below the reporting limit | Source | |
|
|
| Unit | microEquivalentsPerLiter | Type | real | Min | 0.01 | Max | 135 |
| Allowed Values and DefinitionsEnumerated Domain | | Code Definition | Code | DL | Definition | below the detection limit | Source | |
| Code Definition | Code | RL | Definition | below the reporting limit | Source | |
|
|
| Unit | microEquivalentsPerLiter | Type | real | Min | 0.14 | Max | 78.7 |
| Unit | microgramsPerLiter | Type | natural | Min | 13 | Max | 996 |
| Unit | microgramsPerLiter | Type | natural | Min | 8 | Max | 496 |
| Allowed Values and DefinitionsEnumerated Domain | | Code Definition | Code | RL | Definition | below the reporting limit | Source | |
| Code Definition | Code | DL | Definition | below the detection limit | Source | |
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|
| Unit | milligramsPerLiter | Type | real | Min | 0 | Max | 7.5 |
| Allowed Values and DefinitionsEnumerated Domain | | Code Definition | Code | RL | Definition | below the reporting limit | Source | |
|
|
| Unit | milligramsPerLiter | Type | real | Min | 0.1 | Max | 3.8 |
| Allowed Values and DefinitionsEnumerated Domain | | Code Definition | Code | RL | Definition | below the reporting limit | Source | |
| Code Definition | Code | DL | Definition | below the detection limit | Source | |
|
|
| Unit | milligramsPerLiter | Type | real | Min | 0 | Max | 2.06 |
| Allowed Values and DefinitionsEnumerated Domain | | Code Definition | Code | DL | Definition | below the detection limit | Source | |
| Code Definition | Code | RL | Definition | below the reporting limit | Source | |
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|
| Unit | microgramsPerLiter | Type | real | Min | 0 | Max | 74.2 |
| Allowed Values and DefinitionsEnumerated Domain | | Code Definition | Code | RL | Definition | below the reporting limit | Source | |
| Code Definition | Code | DL | Definition | below the detection limit | Source | |
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|
| Unit | milligramsPerLiter | Type | real | Min | 0 | Max | 3.9 |
| Unit | microEquivalentsPerLiter | Type | real | Min | -26.7 | Max | 76.8 |
| Unit | microSiemensPerCentimeter | Type | real | Min | 0.5 | Max | 61 |
| Unit | litersPerSecond | Type | real | Min | 0 | Max | 328.396 |
| Unit | microEquivalentsPerLiter | Type | real | Min | 0.06 | Max | 79.4 |
| Unit | microEquivalentsPerLiter | Type | real | Min | 0.27 | Max | 85.6 |
| Unit | dimensionless | Type | real | Min | 4.1 | Max | 6.89 |
| Unit | dimensionless | Type | real | Min | 4.1 | Max | 7.19 |
| Allowed Values and DefinitionsEnumerated Domain | | Code Definition | Code | RL | Definition | below the reporting limit | Source | |
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| Unit | platinumCobaltUnits | Type | whole | Min | 0 | Max | 148 |
| Allowed Values and DefinitionsEnumerated Domain | | Code Definition | Code | RL | Definition | below the reporting limit | Source | |
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| Unit | platinumCobaltUnits | Type | whole | Min | 0 | Max | 10 |
| Definition | Notes when analytical holding times were exceeded or when missing values were substituted with calculated alternatives (rarely). Data users should determine applicability of data for these values. |
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