Data Package Metadata   View Summary

Time series of total and soluble iron and manganese concentrations from Falling Creek Reservoir and Beaverdam Reservoir in southwestern Virginia, USA from 2014 through 2021

General Information
Data Package:
Local Identifier:edi.718.2
Title:Time series of total and soluble iron and manganese concentrations from Falling Creek Reservoir and Beaverdam Reservoir in southwestern Virginia, USA from 2014 through 2021
Alternate Identifier:DOI PLACE HOLDER
Abstract:

Depth profiles of total and soluble iron and manganese were sampled from 2014-2021 in two drinking-water reservoirs, Falling Creek Reservoir (FCR) and Beaverdam Reservoir (BVR), located in Vinton, Virginia, USA. Both reservoirs are owned and operated by the Western Virginia Water Authority and are managed as secondary drinking-water sources for the city of Roanoke, VA. The dataset includes metals samples that were collected along a depth profile taken at the deepest site of the reservoir near the dam. Additional samples were collected at a gauged weir located on the primary inflow tributary, as well as at a secondary tributary, to Falling Creek Reservoir. Sampling frequency was approximately weekly during the summer and fall (May - October), approximately fortnightly during the spring (March - April), and approximately monthly during the winter (November - March).

Publication Date:2022-01-14
For more information:
Visit: DOI PLACE HOLDER

Time Period
Begin:
2014-04-01
End:
2021-12-06

People and Organizations
Contact:Schreiber, Madeline E. (Virginia Tech) [  email ]
Creator:Schreiber, Madeline E. (Virginia Tech)
Creator:Hammond, Nicholas W. (Virginia Tech)
Creator:Krueger, Kathryn M. (Virginia Tech)
Creator:Munger, Zackary W. (Virginia Tech)
Creator:Ming, Cissy L. (Virginia Tech)
Creator:Breef-Pilz, Adrienne (Virginia Tech)
Creator:Carey, Cayelan C. (Virginia Tech)
Associate:Tilley, Athena (Virginia Tech, analytical chemist)
Associate:Parks, Jeffrey (Virginia Tech, analytical chemist)

Data Entities
Data Table Name:
Metals_2014_2021.csv
Description:
Reservoir iron and manganese chemistry dataset
Other Name:
Metals_QAQC_2014_2021.R
Description:
QAQC script
Detailed Metadata

Data Entities


Data Table

Data:https://pasta-s.lternet.edu/package/data/eml/edi/718/2/57912981e3e857c85924484806492446
Name:Metals_2014_2021.csv
Description:Reservoir iron and manganese chemistry dataset
Number of Records:2939
Number of Columns:13

Table Structure
Object Name:Metals_2014_2021.csv
Size:195069 bytes
Authentication:61f3af12c8a304e5e6fabfbb8553162d Calculated By MD5
Text Format:
Number of Header Lines:1
Record Delimiter:\r\n
Orientation:column
Simple Delimited:
Field Delimiter:,

Table Column Descriptions
 
Column Name:Reservoir  
Site  
DateTime  
Depth_m  
TFe_mgL  
TMn_mgL  
SFe_mgL  
SMn_mgL  
Flag_DateTime  
Flag_TFe  
Flag_TMn  
Flag_SFe  
Flag_SMn  
Definition:Three-letter code corresponding to sampled reservoir50=Deep hole or site nearest to dam in each reservoir, 100=Inflow stream of Falling Creek Reservoir (37.30858,-79.83494), 200 = Secondary inflow (wetland) stream to Falling Creek Reservoir (37.30943,-79.83619)Date and time of sampling. All data were collected in the eastern time zone of the U.S.A., with daylight savings time observedDepth of sample collection (from surface)total iron concentrationtotal manganese concentrationsoluble iron concentrationsoluble manganese concentrationData flag for DateTime; 1 = DateTime set to 12:00 because no sampling time was recordedData flag for total iron (TFe); 1 = sample not taken, 2 = instrument malfunction, 3 = sample below detection, 4 = negative value set to zero, 5 = demonic intrusion, 6 = non-standard method, 7 = sample run multiple times and values averaged, 8 = abnormally high or low concentrationData flag for total manganese (TMn); 1 = sample not taken, 2 = instrument malfunction, 3 = sample below detection, 4 = negative value set to zero, 5 = demonic intrusion, 6 = non-standard method, 7 = sample run multiple times and values averaged, 8 = abnormally high or low concentrationData flag for solube iron (SFe); 1 = sample not taken, 2 = instrument malfunction, 3 = sample below detection, 4 = negative value set to zero, 5 = demonic intrusion, 6 = non-standard method, 7 = sample run multiple times and values averaged, 8 = abnormally high or low concentrationData flag for soluble manganese (SMn); 1 = sample not taken, 2 = instrument malfunction, 3 = sample below detection, 4 = negative value set to zero, 5 = demonic intrusion, 6 = non-standard method, 7 = sample run multiple times and values averaged, 8 = abnormally high or low concentration
Storage Type:string  
float  
date  
float  
float  
float  
float  
float  
float  
float  
float  
float  
float  
Measurement Type:nominalratiodateTimeratioratioratioratioratioratioratioratioratioratio
Measurement Values Domain:
Allowed Values and Definitions
Enumerated Domain 
Code Definition
CodeBVR
DefinitionBeaverdam Reservoir
Source
Code Definition
CodeFCR
DefinitionFalling Creek Reservoir
Source
Unitdimensionless
Typenatural
Min50 
Max200 
FormatMM/DD/YYYY hh:mm:ss
Precision
Unitmeter
Typereal
Min0.1 
Max12 
UnitmilligramsPerLiter
Typereal
Min0.004 
Max64.7 
UnitmilligramsPerLiter
Typereal
Min0.00071 
Max4.367 
UnitmilligramsPerLiter
Typereal
Min
Max59.77 
UnitmilligramsPerLiter
Typereal
Min2e-05 
Max4.247 
Unitdimensionless
Typewhole
Min
Max
Unitdimensionless
Typewhole
Min
Max
Unitdimensionless
Typewhole
Min
Max
Unitdimensionless
Typewhole
Min
Max
Unitdimensionless
Typewhole
Min
Max
Missing Value Code:
CodeNA
Explvalue is missing
CodeNA
Explvalue is missing
CodeNA
Explvalue is missing
CodeNA
Explvalue is missing
CodeNA
Explvalue is missing
CodeNA
Explvalue is missing
CodeNA
Explvalue is missing
CodeNA
Explvalue is missing
CodeNA
Explvalue is missing
CodeNA
Explvalue is missing
CodeNA
Explvalue is missing
CodeNA
Explvalue is missing
CodeNA
Explvalue is missing
Accuracy Report:                          
Accuracy Assessment:                          
Coverage:                          
Methods:                          

Non-Categorized Data Resource

Name:Metals_QAQC_2014_2021.R
Entity Type:unknown
Description:QAQC script
Physical Structure Description:
Object Name:Metals_QAQC_2014_2021.R
Size:14287 bytes
Authentication:c050415b99189ecabc405a489dc5b016 Calculated By MD5
Externally Defined Format:
Format Name:text/plain
Data:https://pasta-s.lternet.edu/package/data/eml/edi/718/2/e96ef9e063ae931af23439cf8d59abc2

Data Package Usage Rights

This information is released under the Creative Commons license - Attribution - CC BY (https://creativecommons.org/licenses/by/4.0/). The consumer of these data (\"Data User\" herein) is required to cite it appropriately in any publication that results from its use. The Data User should realize that these data may be actively used by others for ongoing research and that coordination may be necessary to prevent duplicate publication. The Data User is urged to contact the authors of these data if any questions about methodology or results occur. Where appropriate, the Data User is encouraged to consider collaboration or co-authorship with the authors. The Data User should realize that misinterpretation of data may occur if used out of context of the original study. While substantial efforts are made to ensure the accuracy of data and associated documentation, complete accuracy of data sets cannot be guaranteed. All data are made available \"as is.\" The Data User should be aware, however, that data are updated periodically and it is the responsibility of the Data User to check for new versions of the data. The data authors and the repository where these data were obtained shall not be liable for damages resulting from any use or misinterpretation of the data. Thank you.

Keywords

By Thesaurus:
carey lab controlled vocabularyCarey Lab, Virginia Tech, Western Virginia Water Authority, Falling Creek Reservoir, Beaverdam Reservoir
cuahsi controlled vocabularyReservoir, Lake, iron, manganese
lter controlled vocabularyLakes

Methods and Protocols

These methods, instrumentation and/or protocols apply to all data in this dataset:

Methods and protocols used in the collection of this data package
Description:

WATER COLUMN SAMPLING: We collected water samples for total and soluble Fe and Mn concentrations from Falling Creek Reservoir (FCR) and Beaverdam Reservoir (BVR) approximately fortnightly from March-April, weekly from May-October, and monthly from November-February. Water samples were collected at the deepest site of each reservoir using a 4-L Van Dorn sampler (Wildlife Supply Company, Yulee, FL). In FCR, water samples were collected at specified depths ranging from 0.1 m to 9.8 m. Additional water samples were collected from the primary inflow tributary as well as a secondary tributary. In BVR, water samples were collected at specified depths ranging from 0.1 m to 12.0 m. After collection, we poured raw water samples directly from the Van Dorn sampler into sample bottles for total metal analyses and we syringe-filtered water using 0.45 micron nylon filters into bottles for soluble metal analyses. All samples were preserved using trace metal grade nitric acid to pH less than 2. SAMPLING TIMES: Most sampling occurred between the hours of 9:00 and 15:00. Some sampling occurred outside of these hours, including some overnight sampling; these instances are noted by the actual sampling time within the DateTime column. Samples with no exact sampling time recorded are reported as 12:00 in the DateTime column and flagged with a '1' in the Flag_DateTime column. Samples were collected in the America/New York Eastern Time Zone, which observed daylight savings time from approximately March to November in 2014-2020.

CHEMICAL ANALYSIS: In 2014-2015, samples were analyzed for Fe and Mn using an Inductively Coupled Plasma-Mass Spectrometer (ICP-MS; Thermo Electron X-Series) following APHA Standard Method 3125-B (American Public Health Association et al., 1998). Detection limits for Fe and Mn were 0.0008 mg/L and 0.0005 mg/L, respectively, in 2014 and 0.0012 mg/L and 0.00007 mg/L, respectively, in 2015. In 2016-2019, samples were analyzed for Fe and Mn using an Inductively Coupled Plasma Optical Emission Spectrometer (ICP-OES) using a Spectro ARCOS SOP (Side-On Plasma interface) instrument using methods similar to EPA 200.7 (EPA, 1994). During 2016-2019, detection limits for Fe and Mn were 0.004 mg/L and 0.001 mg/L, respectively. Starting in 2020, samples were analyzed for Fe and Mn using an Inductively Coupled Plasma-Mass Spectrometer (ICP-MS; Thermo Electron iCAP-RQ) following APHA Standard Method 3125-B (American Public Health Association et al., 1998). In 2020-2021, detection limits for Fe and Mn were 0.0004 mg/L and 0.00003 mg/L, respectively. The minimum reporting levels for Fe and Mn were 0.005 mg/L and 0.0001 mg/L, respectively. We used the minimum reporting levels as the lower threshold for data in 2020-2021. Values that were below the minimum detection limit (for 2014-2019) or minimum reporting level (for 2020-2021) were set to the value of the minimum detection limit or minimum reporting level. Negative values were set to 0. REFERENCES: American Public Health Association (APHA), American Water Works Association, Water Environment Federation, 1998. Standard Methods for the Examination of Water and Wastewater, 20th ed. American Public Health Association, Washington, DC.

Environmental Protection Agency (EPA) (1994), Method 200.7: Determination of Metals and Trace Elements in Water and Waste by Inductively Coupled Plasma-Atomic Emission Spectrometry, Revision 4.4, May 1994, Environmental Monitoring Systems Laboratory, Office of Research and Development, U.S. Environmental Protection Agency, Cincinnati, OH 45268, T.D. Martin, C.A. Brockhoff, J.T. Creed and EMMC Methods Work Group

People and Organizations

Publishers:
Organization:Environmental Data Initiative
Email Address:
info@environmentaldatainitiative.org
Web Address:
https://environmentaldatainitiative.org
Id:https://ror.org/0330j0z60
Creators:
Individual: Madeline E. Schreiber
Organization:Virginia Tech
Email Address:
mschreib@vt.edu
Id:https://orcid.org/0000-0002-1858-7730
Individual: Nicholas W. Hammond
Organization:Virginia Tech
Email Address:
hammondnw@vt.edu
Id:https://orcid.org/0000-0003-2975-8280
Individual: Kathryn M. Krueger
Organization:Virginia Tech
Email Address:
kmkvb13@gmail.com
Id:https://orcid.org/0000-0002-3509-0611
Individual: Zackary W. Munger
Organization:Virginia Tech
Email Address:
mungalor@gmail.com
Id:https://orcid.org/0000-0002-3604-2697
Individual: Cissy L. Ming
Organization:Virginia Tech
Email Address:
cissym@vt.edu
Id:https://orcid.org/0000-0003-0316-2315
Individual: Adrienne Breef-Pilz
Organization:Virginia Tech
Email Address:
abreefpilz@vt.edu
Id:https://orcid.org/0000-0002-6759-0063
Individual: Cayelan C. Carey
Organization:Virginia Tech
Email Address:
Cayelan@vt.edu
Id:https://orcid.org/0000-0001-8835-4476
Contacts:
Individual: Madeline E. Schreiber
Organization:Virginia Tech
Email Address:
mschreib@vt.edu
Id:https://orcid.org/0000-0002-1858-7730
Associated Parties:
Individual: Athena Tilley
Organization:Virginia Tech
Email Address:
atilley@vt.edu
Id:https://orcid.org/0000-0001-7865-5136
Role:analytical chemist
Individual: Jeffrey Parks
Organization:Virginia Tech
Email Address:
jparks@vt.edu
Id:https://orcid.org/0000-0002-1269-6987
Role:analytical chemist

Temporal, Geographic and Taxonomic Coverage

Temporal, Geographic and/or Taxonomic information that applies to all data in this dataset:

Time Period
Begin:
2014-04-01
End:
2021-12-06
Geographic Region:
Description:Beaverdam Reservoir is located in Vinton, Virginia, USA
Bounding Coordinates:
Northern:  37.322865Southern:  37.311961
Western:  -79.824834Eastern:  -79.813848
Geographic Region:
Description:Falling Creek Reservoir is located in Vinton, Virginia, USA
Bounding Coordinates:
Northern:  37.309589Southern:  37.30266
Western:  -79.839249Eastern:  -79.836009

Project

Parent Project Information:

Title:No project title to report
Personnel:
Individual: Nicholas W. Hammond
Organization:Virginia Tech
Email Address:
hammondnw@vt.edu
Id:https://orcid.org/0000-0003-2975-8280
Role:Principal Investigator
Funding: Geological Society of America
Related Project:
Title:No project title to report
Personnel:
Individual: Kathryn M. Krueger
Organization:Virginia Tech
Email Address:
kmkvb13@gmail.com
Id:https://orcid.org/0000-0002-3509-0611
Role:Principal Investigator
Funding: Virginia Water Resources Research Center
Related Project:
Title:No project title to report
Personnel:
Individual: Cayelan C. Carey
Organization:Virginia Tech
Email Address:
Cayelan@vt.edu
Id:https://orcid.org/0000-0001-8835-4476
Role:Principal Investigator
Funding: Western Virginia Water Authority
Related Project:
Title:Dynamics of coupled P-Fe-Mn cycling in drinking water reservoirs and implications for water quality
Personnel:
Individual: Cayelan C. Carey
Organization:Virginia Tech
Email Address:
Cayelan@vt.edu
Id:https://orcid.org/0000-0001-8835-4476
Role:Principal Investigator
Funding: Institute of Critical Technology and Applied Science
Related Project:
Title:No project title to report
Personnel:
Individual: Cayelan C. Carey
Organization:Virginia Tech
Email Address:
Cayelan@vt.edu
Id:https://orcid.org/0000-0001-8835-4476
Role:Principal Investigator
Funding: Virginia Tech Global Change Center
Related Project:
Title:No project title to report
Personnel:
Individual: Cayelan C. Carey
Organization:Virginia Tech
Email Address:
Cayelan@vt.edu
Id:https://orcid.org/0000-0001-8835-4476
Role:Principal Investigator
Funding: Fralin Life Sciences Institute
Related Project:
Title:SCC-IRG Track 2: Resilient Water Systems: Integrating Environmental Sensor Networks and Real-Time Forecasting to Adaptively Manage Drinking Water Quality and Build Social Trust
Personnel:
Individual: Cayelan C. Carey
Organization:Virginia Tech
Email Address:
Cayelan@vt.edu
Id:https://orcid.org/0000-0001-8835-4476
Role:Principal Investigator
Funding: National Science Foundation 1737424
Related Project:
Title:Collaborative Research: Consequences of changing oxygen availability for carbon cycling in freshwater ecosystems
Personnel:
Individual: Cayelan C. Carey
Organization:Virginia Tech
Email Address:
Cayelan@vt.edu
Id:https://orcid.org/0000-0001-8835-4476
Role:Principal Investigator
Funding: National Science Foundation 1753639
Related Project:
Title:Collaborative Research: CIBR: Cyberinfrastructure Enabling End-to-End Workflows for Aquatic Ecosystem Forecasting
Personnel:
Individual: Cayelan C. Carey
Organization:Virginia Tech
Email Address:
Cayelan@vt.edu
Id:https://orcid.org/0000-0001-8835-4476
Role:Principal Investigator
Funding: National Science Foundation 1933016
Related Project:
Title:Collaborative Research: CIBR: Cyberinfrastructure Enabling End-to-End Workflows for Aquatic Ecosystem Forecasting
Personnel:
Individual: Renato J. Figueiredo
Organization:University of Florida
Email Address:
renato@acis.ufl.edu
Id:https://orcid.org/0000-0001-9841-6060
Role:Principal Investigator
Funding: National Science Foundation 1933102

Maintenance

Maintenance:
Description:ongoing
Frequency:

Additional Info

Additional Information:
 

From 2014 to 2021, multiple whole-ecosystem manipulations were conducted at Falling Creek Reservoir. These manipulations include intermittent operation of hypolimnetic oxygenation and pulsed epilimnetic mixing engineering systems. For a detailed description of the hypolimnetic oxygenation engineered system, see Gerling et al. (2014) and for a detailed description of the epilimnetic mixing engineered system, see Chen et al. (2017). These systems were operated over time following Table 1 in Gerling et al. (2016), Table 1 in Munger et al. (2016), Table 2 in McClure et al. (2018), and Table SI.1 in Hounshell et al. (2020). Additional hypolimnetic oxygenation and epilimnetic mixing events not currently detailed in peer-reviewed articles are listed below:

2017: EM was activated on 29 May and from 10-12 July.

2019: HOx was activated during the following time periods: 03 June to 17 June, 08 July to 22 July, 05 August to 19 August, 02 September to 20 November.

2020: HOx was activated during the following time periods: 29 June to 11 September, 25 September to 02 December.

2021: HOx was activated during the following time periods: 11 June to 26 June, 12 July to 14 July, 26 July to 6 December

Author Contributions: MES has been PI for this project since its inception and has developed and implemented the metals reservoir monitoring program; NWH led sampling, data analysis, and QAQC from 2019 until fall 2021; KMK led sampling, data analysis, and QAQC from 2015 to 2018; ZWM led sampling, data analysis, and QAQC from 2014 to 2015; CM led data analysis and QAQC from fall 2021 until present; ABP led the field crew and contributed substantially to sampling in 2021.

References:

Chen, S., C. Lei, C.C. Carey, P.A. Gantzer, and J.C. Little. 2017. Predicting hypolimnetic oxygenation and epilimnetic mixing in a shallow eutrophic reservoir using a coupled three-dimensional hydrodynamic model. Water Resources Research. 53: 470-484. DOI: 10.1002/2016WR019279

Gerling, A.B., Browne, R.G., Gantzer, P.A., Mobley, M.H., Little, J.C., and C.C. Carey. 2014. First report of the successful operation of a side stream supersaturation hypolimnetic oxygenation system in a eutrophic, shallow reservoir. Water Research. 67: 129-143. doi: 10.1016/j.watres.2014.09.002

Gerling, A.B., Z.W. Munger, J.P. Doubek, K.D. Hamre, P.A. Gantzer, J.C. Little, and C.C. Carey. 2016. Whole-catchment manipulations of internal and external loading reveal the sensitivity of a century-old reservoir to hypoxia. Ecosystems. 19:555-571. DOI: 10.1007/s10021-015-9951-0

Hounshell, A.G., McClure, R.P., Lofton, M.E., and C.C. Carey. 2020. Whole-ecosystem oxygenation experiments reveal substantially greater hypolimnetic methane concentrations in reservoirs during anoxia. Limnology and Oceanography Letters. DOI: 10.1002/lol2.10173

Krueger, K.M. 2019. Metal fluxes across the sediment water interface in a drinking water reservoir. MS Thesis, Department of Geosciences, Virginia Tech. http://hdl.handle.net/10919/90297

McClure, R.P., K.D. Hamre, B.R. Niederlehner, Z.W. Munger, S. Chen, M.E. Lofton, M.E. Schreiber, and C.C. Carey. 2018 Metalimnetic oxygen minima alter the vertical profiles of carbon dioxide and methane in a managed freshwater reservoir. Science of the Total Environment 636: 610-620. DOI: 10.1016/j.scitotenv.2018.04.255

Munger, Z.W., C.C. Carey, A.B. Gerling, K.D. Hamre, J.P. Doubek, S.D. Klepatzki, R.P. McClure, and M.E. Schreiber. 2016. Effectiveness of hypolimnetic oxygenation for preventing accumulation of Fe and Mn in a drinking water reservoir. Water Research. 106: 1-14. DOI: 10.1016/j.watres.2016.09.038.

Lofton, M.E., McClure, R.P., Chen, S., Little, J.C., and C.C. Carey. 2019. Whole-ecosystem experiments reveal varying responses of phytoplankton functional groups to epilimnetic mixing in a eutrophic reservoir. Water. 11, 222; DOI:10.3390/w11020222.

Other Metadata

EDI is a collaboration between the University of New Mexico and the University of Wisconsin – Madison, Center for Limnology:

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