Data Package Metadata   View Summary

Chemistry of freely-draining soil solutions at the Hubbard Brook Experimental Forest, Watershed 6, 1982 - present

General Information
Data Package:
Local Identifier:knb-lter-hbr.62.13
Title:Chemistry of freely-draining soil solutions at the Hubbard Brook Experimental Forest, Watershed 6, 1982 - present
Alternate Identifier:knb-lter-hbr.62
Alternate Identifier:DOI PLACE HOLDER
Abstract:

Tension-free lysimeters were installed in three soil horizons at three locations adjacent to Hubbard Brook Experiment Forest Watershed 6. At each location, the organic horizon and the B horizon were selected for lysimeter placement. Soil solution samples were collected approximately monthly and analyzed for base cations, soluble anions, trace metals, nitrogen and carbon.

These data were gathered as part of the Hubbard Brook Ecosystem Study (HBES). The HBES is a collaborative effort at the Hubbard Brook Experimental Forest, which is operated and maintained by the USDA Forest Service, Northern Research Station.

Short Name:Soil Solution Chem WS6
Publication Date:2019-03-03
Language:English

Time Period
Begin:
1984-01-28
End:
2015-01-16

People and Organizations
Contact:Information Manager (Hubbard Brook Ecosystem Study) [  email ]
Creator:Driscoll, Charles T 

Data Entities
Data Table Name:
HBEF Watershed 6 soil solution chemistry
Description:
Soil solution chemistry at Hubbard Brook Experimental Forest adjacent to Watershed 6, measured with tension-free lysimeters
Detailed Metadata

Data Entities


Data Table

Data:https://pasta-s.lternet.edu/package/data/eml/knb-lter-hbr/62/13/4fa59538abe2e6ff15a35ea2de913546
Name:HBEF Watershed 6 soil solution chemistry
Description:Soil solution chemistry at Hubbard Brook Experimental Forest adjacent to Watershed 6, measured with tension-free lysimeters
Number of Records:3979
Number of Columns:23

Table Structure
Object Name:HBEF_1984-2017_Soil_Chem_W6.csv
Size:537226 byte
Authentication:49ed5c74d1e972392aee95ab318caa89 Calculated By MD5
Text Format:
Number of Header Lines:1
Record Delimiter:\r\n
Orientation:column
Simple Delimited:
Field Delimiter:,

Table Column Descriptions
 DateWSElevHorpHANCH4SiO4Na+K+Ca2+CaFLAGMg2+AltAlmAloNH4+F-Cl-SO4=NO3-DICDOCTN
Column Name:Date  
WS  
Elev  
Hor  
pH  
ANC  
H4SiO4  
Na+  
K+  
Ca2+  
CaFLAG  
Mg2+  
Alt  
Alm  
Alo  
NH4+  
F-  
Cl-  
SO4=  
NO3-  
DIC  
DOC  
TN  
Definition:Sample dateWatershed identification numberElevationSoil horizonpH measurementAcid Neutralizing CapacityDissolved silica concentration in umol/LSodium concentration in umol/LPotassium concentration in umol/LCalcium concentration in umol/LNotes on calcium measurementsMagnesium concentration in umol/LTotal aluminum concentration in umol/LTotal monomeric aluminum concentration in umol/LOrganic monomeric aluminum in umol/LAmmonium concentration in umol/LTotal fluoride concentration in umol/LChloride concentration in umol/LSulfate concentration in umol/LNitrate concentration in umol/LDissolved inorganic carbon in umol/LDissolved organic carbon in umol/LTotal nitrogen in umol/L
Storage Type:string  
string  
string  
string  
float  
float  
float  
float  
float  
float  
string  
float  
float  
float  
float  
float  
float  
float  
float  
float  
float  
float  
float  
Measurement Type:dateTimenominalnominalnominalintervalratioratioratioratiorationominalratioratioratioratioratioratioratioratioratioratioratioratio
Measurement Values Domain:
FormatYYYY-MM-DD
Precision
Definitionany text
Definitionany text
Definitionany text
Unitdimensionless
Precision0.01
Typereal
UnitmicroEquivalentPerLiter
Precision0.1
Typereal
UnitmicromolePerLiter
Precision3
Typereal
UnitmicromolePerLiter
Precision0.015
Typereal
UnitmicromolePerLiter
Precision0.12
Typereal
UnitmicromolePerLiter
Precision0.03
Typereal
Definitionany text
UnitmicromolePerLiter
Precision0.0032
Typereal
UnitmicromolePerLiter
Precision0.0026
Typereal
UnitmicromolePerLiter
Precision1.3
Typereal
UnitmicromolePerLiter
Precision1.3
Typereal
UnitmicromolePerLiter
Precision0.55
Typereal
UnitmicromolePerLiter
Precision0.097
Typereal
UnitmicromolePerLiter
Precision0.55
Typereal
UnitmicromolePerLiter
Precision0.53
Typereal
UnitmicromolePerLiter
Precision0.85
Typereal
UnitmicromolePerLiter
Precision20
Typereal
UnitmicromolePerLiter
Precision20
Typereal
UnitmicromolePerLiter
Precision0.81
Typereal
Missing Value Code:        
Code-999.99
ExplData missing, or not taken at this time
Code-999.99
ExplData missing, or not taken at this time
Code-999.99
ExplData missing, or not taken at this time
Code-999.99
ExplData missing, or not taken at this time
Code-999.99
ExplData missing, or not taken at this time
Code-999.99
ExplData missing, or not taken at this time
 
Code-999.99
ExplData missing, or not taken at this time
Code-999.99
ExplData missing, or not taken at this time
Code-999.99
ExplData missing, or not taken at this time
Code-999.99
ExplData missing, or not taken at this time
Code-999.99
ExplData missing, or not taken at this time
Code-999.99
ExplData missing, or not taken at this time
Code-999.99
ExplData missing, or not taken at this time
Code-999.99
ExplData missing, or not taken at this time
Code-999.99
ExplData missing, or not taken at this time
Code-999.99
ExplData missing, or not taken at this time
Code-999.99
ExplData missing, or not taken at this time
Code-999.99
ExplData missing, or not taken at this time
Accuracy Report:                                              
Accuracy Assessment:                                              
Coverage:                                              
Methods:                                              

Data Package Usage Rights

This information is released under the Creative Commons license - Attribution - CC BY (https://creativecommons.org/licenses/by/4.0/). The consumer of these data ("Data User" herein) is required to cite it appropriately in any publication that results from its use. The Data User should realize that these data may be actively used by others for ongoing research and that coordination may be necessary to prevent duplicate publication. The Data User is urged to contact the authors of these data if any questions about methodology or results occur. Where appropriate, the Data User is encouraged to consider collaboration or co-authorship with the authors. The Data User should realize that misinterpretation of data may occur if used out of context of the original study.

While substantial efforts are made to ensure the accuracy of data and associated documentation, complete accuracy of data sets cannot be guaranteed. All data are made available "as is." The Data User should be aware, however, that data are updated periodically and it is the responsibility of the Data User to check for new versions of the data. The data authors and the repository where these data were obtained shall not be liable for damages resulting from any use or misinterpretation of the data. Thank you.

Keywords

By Thesaurus:
Hubbard Brook Ecosystem Studybase cations, HBEF Watershed 6, HBR, Hubbard Brook LTER, leachate
LTER Network Controlled Vocabularyaluminum, ammonium, calcium, carbon, chemistry, chloride, dissolved inorganic carbon, dissolved organic carbon, fluoride, forests, lysimeters, magnesium, nitrate, nitrogen, potassium, silica, sodium, soil, soil horizons, soil water, sulfate, water, watersheds

Methods and Protocols

These methods, instrumentation and/or protocols apply to all data in this dataset:

Methods and protocols used in the collection of this data package
Description:

LOCATION DESCRIPTION

Tension-free lysimeters are installed in the Oa, Bh and Bs horizons at 3 sites located adjacent to watershed 6 at elevations of 750m (spruce-fir-white beech zone; SFB), 730m (high elevation hardwood zone; HH) and 600m (low elevation hardwood zone; LH). Three replicate lysimeters were installed beneath the Oa and Bh horizons and within the Bs horizon at the HH and LH sites, and two replicate lysimeters were installed in each horizon at the SFB site.

SAMPLING DESIGN

The lysimeters were constructed from either polyethylene funnels filled with acid-washed silica sand that drain into 1-L polyethylene containers or rectangular polyethylene containers filled with acid-washed Teflon beads that drain into 2-L polyethylene bottles. At each site, lysimeters were carefully installed in the wall of excavated soil pits, immediately below the Oa and Bh horizons and within the lower Bs horizon. Soil pits were backfilled to prevent accumulation of water and to eliminate freezing during winter months. Soil solution samples are collected approximately monthly in acid-washed polyethylene bottles and refrigerated at 4 degrees C.

NOTES ON DATA

Between 1984 and 1986 and 1998-present, data are the arithmetic means for samples collected from individual lysimeters. From 1986 through 1998, data are for bulked soil solutions collected from replicate lysimeters. Current detection limits for the Driscoll laboratory: Na (0.015 umol/L), K (0.12 umol/L), Ca (0.030 umol/L), Mg (0.0032 umol/L), Alt (0.0026 umol/L), Alm (1.3 umol/L), Alo (1.3 umol/L), NH4 (0.55 umol/L), H4SiO2 (3 umol/L), Cl (0.55 umol/L), NO3 (0.85 umol/L), SO4 (0.53 umol/L), F (0.097 umol/L), DIC (20 umol/L), DOC (20 umol/L), TN (0.81 umol/L). It is suggested to dataset users to use a value of one half the detection limit when a value for a solute is less than the detection limit. The data is physically located at the Department of Civil and Environmental Engineering, Syracuse University, Syracuse, NY.

REFERENCES

Dahlgren, R.A., and Driscoll, C.T. 1994. The effects of whole-tree clear-cutting on soil processes at the Hubbard Brook Experimental Forest, New Hampshire, USA. Plant Soil 158:239-262.

Dittman, J.A. Dynamics of Nitrogen and Dissolved Organic Carbon in a Forested Watershed at the Hubbard Brook Experimental Forest. Master of Science, Syracuse University.

Dittman, J.A., Driscoll, C.T., Groffman, P.M., and Fahey, T.J. 2007. Dynamics of nitrogen and dissolved organic carbon at the Hubbard Brook Experimental Forest. Ecology 88(5):1153-1166.

Driscoll, C.T., Fuller, R.D., and Simone, D.M. 1988. Longitudinal variations in trace metal concentrations in a northern hardwood forested ecosystem. J. Environ. Qual. 17(1):101-107.

Fuss, C.B. 2009. Biogeochemical dynamics of oxidized and reduced iron at the Hubbard Brook Experimental Forest. Masters of Science, Syracuse University.

Fuss, C.B., Driscoll, C.T., Johnson, C.E., Petras, R.J., and Fahey, T.J. 2011. Dynamics of Oxidized and Reduced Iron in a Northern Hardwood Forest. Biogeochemistry 104(1-3 (July)):103-119.

Johnson, C.E., Driscoll, C.T., Siccama, T.G., and Likens, G.E. 2000. Element fluxes and landscape position in a northern hardwood forest watershed ecosystem. Ecosystems 3:159-184.

Palmer, S.M. Spatial and temporal patterns in the biogeochemistry of aluminum at the Hubbard Brook Experimental Forest, New Hampshire. Dissertation, Syracuse University.

Palmer, S.M., Driscoll, C.T., and Johnson, C.E. 2004. Long-term trends in soil solution and stream water chemistry at the Hubbard Brook Experimental Forest: relationship with landscape position. Biogeochemistry 68(1):51-70.

People and Organizations

Publishers:
Organization:Hubbard Brook Ecosystem Study
Address:
234 Mirror Lake Road,
North Woodstock, NH 03262 United States
Creators:
Individual: Charles T Driscoll
Contacts:
Organization:Hubbard Brook Ecosystem Study
Position:Information Manager
Address:
234 Mirror Lake Road,
North Woodstock, NH 03262 United States
Email Address:
hbr-im@lternet.edu
Web Address:
https://hubbardbrook.org

Temporal, Geographic and Taxonomic Coverage

Temporal, Geographic and/or Taxonomic information that applies to all data in this dataset:

Time Period
Begin:
1984-01-28
End:
2015-01-16
Geographic Region:
Description:Adjacent to HBEF watershed 6.
Bounding Coordinates:
Northern:  43.957001Southern:  43.949928
Western:  -71.743462Eastern:  -71.735649
Sampling Site: 
Description:Location of 750m altitude spruce-fir-white beech zone (SFB) Lysimeters
Site Coordinates:
Longitude (degree): -71.739931Latitude (degree): 43.957423
Sampling Site: 
Description:Location of 600m altitude low-elevation hardwood zone (LH) Lysimeters
Site Coordinates:
Longitude (degree): -71.738842Latitude (degree): 43.950622
Sampling Site: 
Description:Location of 730m altitude high-elevation hardwood zone (HH) Lysimeters
Site Coordinates:
Longitude (degree): -71.741369Latitude (degree): 43.954523

Project

Other Metadata

Additional Metadata

additionalMetadata
        |___text '\n    '
        |___element 'metadata'
        |     |___text '\n      '
        |     |___element 'unitList'
        |     |     |___text '\n        '
        |     |     |___element 'unit'
        |     |     |     |  \___attribute 'id' = 'dimensionless'
        |     |     |     |  \___attribute 'name' = 'dimensionless'
        |     |     |     |  \___attribute 'unitType' = 'dimensionless'
        |     |     |     |___text '\n          '
        |     |     |     |___element 'description'
        |     |     |     |     |___text 'a designation asserting the absence of an associated unit'
        |     |     |     |___text '\n        '
        |     |     |___text '\n        '
        |     |     |___element 'unit'
        |     |     |        \___attribute 'id' = 'microEquivalentPerLiter'
        |     |     |        \___attribute 'name' = 'microEquivalentPerLiter'
        |     |     |        \___attribute 'unitType' = 'NA'
        |     |     |___text '\n        '
        |     |     |___element 'unit'
        |     |     |     |  \___attribute 'constantToSI' = '0'
        |     |     |     |  \___attribute 'id' = 'micromolePerLiter'
        |     |     |     |  \___attribute 'name' = 'micromolePerLiter'
        |     |     |     |  \___attribute 'parentSI' = 'molePerMeterCubed'
        |     |     |     |  \___attribute 'unitType' = 'amountOfSubstanceConcentration'
        |     |     |     |___text '\n          '
        |     |     |     |___element 'description'
        |     |     |     |     |___text 'commonly used for concentration of some chemical constituents of natural water bodies, e.g., nutrients. It has the same magnitude as micromolar, but micromolar can only be used for a dissolved constituent'
        |     |     |     |___text '\n        '
        |     |     |___text '\n      '
        |     |___text '\n    '
        |___text '\n  '

EDI is a collaboration between the University of New Mexico and the University of Wisconsin – Madison, Center for Limnology:

UNM logo UW-M logo