Data Package Metadata   View Summary

Chemistry of freely-draining soil solutions at the Hubbard Brook Experimental Forest, Watershed 6, 1982 - present

General Information
Data Package:
Local Identifier:knb-lter-hbr.62.18
Title:Chemistry of freely-draining soil solutions at the Hubbard Brook Experimental Forest, Watershed 6, 1982 - present
Alternate Identifier:DOI PLACE HOLDER
Abstract:

Tension-free lysimeters were installed in three soil horizons at three locations adjacent to Hubbard Brook Experiment Forest Watershed 6. At each location, the organic horizon and the B horizon were selected for lysimeter placement. Soil solution samples were collected approximately monthly and analyzed for base cations, soluble anions, trace metals, nitrogen and carbon.

These data were gathered as part of the Hubbard Brook Ecosystem Study (HBES). The HBES is a collaborative effort at the Hubbard Brook Experimental Forest, which is operated and maintained by the USDA Forest Service, Northern Research Station.

Publication Date:2022-02-20
For more information:
Visit: DOI PLACE HOLDER

Time Period
Begin:
1984-01-28
End:
2020-12-31

People and Organizations
Contact:Hubbard Brook Ecosystem Study [  email ]
Creator:Driscoll, Charles T (Syracuse University)

Data Entities
Data Table Name:
W6Lysim_HB1984-2020
Description:
soil solution chemistry at Hubbard Brook Experimental Forest adjacent to Watershed 6, measured with tension-free lysimeters
Detailed Metadata

Data Entities


Data Table

Data:https://pasta-s.lternet.edu/package/data/eml/knb-lter-hbr/62/18/77718349a6a3be06ee1942dfc15511e0
Name:W6Lysim_HB1984-2020
Description:soil solution chemistry at Hubbard Brook Experimental Forest adjacent to Watershed 6, measured with tension-free lysimeters
Number of Records:4734
Number of Columns:23

Table Structure
Object Name:W6Lysim_HB1984-2020.csv
Size:596678 bytes
Authentication:6086889f540c298feddba33c9c1c50d1 Calculated By MD5
Text Format:
Number of Header Lines:1
Record Delimiter:\r\n
Orientation:column
Simple Delimited:
Field Delimiter:,
Quote Character:"

Table Column Descriptions
 
Column Name:Date  
WS  
Site  
Horizon  
pH  
ANC  
H4SiO4  
Na+  
K+  
Ca2+  
CaFLAG  
Mg2+  
Alt  
Alm  
Alo  
NH4+  
F-  
Cl-  
SO4=  
NO3-  
DIC  
DOC  
TN  
Definition:Sample dateWatershed identification numberElevationSoil horizonpH measurementAcid Neutralizing CapacityDissolved silica concentration in umol/LSodium concentration in umol/LPotassium concentration in umol/LCalcium concentration in umol/LNotes on calcium measurementsMagnesium concentration in umol/LTotal aluminum concentration in umol/LTotal monomeric aluminum concentration in umol/LOrganic monomeric aluminum in umol/LAmmonium concentration in umol/LTotal fluoride concentration in umol/LChloride concentration in umol/LSulfate concentration in umol/LNitrate concentration in umol/LDissolved inorganic carbon in umol/LDissolved organic carbon in umol/LTotal nitrogen in umol/L
Storage Type:date  
string  
string  
string  
float  
float  
float  
float  
float  
float  
string  
float  
float  
float  
float  
float  
float  
float  
float  
float  
float  
float  
float  
Measurement Type:dateTimenominalnominalnominalratioratioratioratioratiorationominalratioratioratioratioratioratioratioratioratioratioratioratio
Measurement Values Domain:
FormatYYYY-MM-DD
Precision
DefinitionWatershed identification number
Allowed Values and Definitions
Enumerated Domain 
Code Definition
CodeSFB
Definition750m altitude spruce-fir-white beech zone
Source
Code Definition
CodeLH
Definition600m altitude low-elevation hardwood zone
Source
Code Definition
CodeHH
Definition730m altitude high-elevation hardwood zone
Source
Allowed Values and Definitions
Enumerated Domain 
Code Definition
CodeBh
DefinitionBh horizon
Source
Code Definition
CodeBs
DefinitionBs horizon
Source
Code Definition
CodeOa
DefinitionOa horizon
Source
Unitdimensionless
Typereal
Min-888.88 
Max7.83 
UnitmicroEquivalentPerLiter
Typereal
Min
Max305.54 
UnitmicromolePerLiter
Typereal
Min1.15 
Max266.6 
UnitmicromolePerLiter
Typereal
Min-0.05 
Max197.11 
UnitmicromolePerLiter
Typereal
Min-3.00 
Max482.5 
UnitmicromolePerLiter
Typereal
Min-0.85 
Max196.82 
DefinitionNotes on calcium measurements
UnitmicromolePerLiter
Typereal
Min0.00 
Max155.37 
UnitmicromolePerLiter
Typereal
Min-3.00 
Max333.7 
UnitmicromolePerLiter
Typereal
Min-0.04 
Max64 
UnitmicromolePerLiter
Typereal
Min-3.00 
Max51.8 
UnitmicromolePerLiter
Typereal
Min0.3 
Max360 
UnitmicromolePerLiter
Typereal
Min0.7 
Max52.6 
UnitmicromolePerLiter
Typereal
Min0.02 
Max700.4 
UnitmicromolePerLiter
Typereal
Min30.5 
Max161.2 
UnitmicromolePerLiter
Typereal
Min-3.0 
Max544.3 
UnitmicromolePerLiter
Typereal
Min-3.0 
Max1310.48 
UnitmicromolePerLiter
Typereal
Min0.00 
Max10224.92 
UnitmicromolePerLiter
Typereal
Min0.00 
Max1273.9 
Missing Value Code:        
Code-999.99
ExplData missing or not taken at this time
Code-888.88
ExplSample volume too small for analysis
Code-777.77
ExplAnalyte concentration below detection limit
Code-999.99
ExplData missing or not taken at this time
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ExplSample volume too small for analysis
Code-777.77
ExplAnalyte concentration below detection limit
Code-999.99
ExplData missing or not taken at this time
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ExplSample volume too small for analysis
Code-777.77
ExplAnalyte concentration below detection limit
Code-999.99
ExplData missing or not taken at this time
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ExplSample volume too small for analysis
Code-777.77
ExplAnalyte concentration below detection limit
Code-999.99
ExplData missing or not taken at this time
Code-888.88
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Code-777.77
ExplAnalyte concentration below detection limit
Code-999.99
ExplData missing or not taken at this time
Code-888.88
ExplSample volume too small for analysis
Code-777.77
ExplAnalyte concentration below detection limit
 
Code-999.99
ExplData missing or not taken at this time
Code-888.88
ExplSample volume too small for analysis
Code-777.77
ExplAnalyte concentration below detection limit
Code-999.99
ExplData missing or not taken at this time
Code-888.88
ExplSample volume too small for analysis
Code-777.77
ExplAnalyte concentration below detection limit
Code-999.99
ExplData missing or not taken at this time
Code-888.88
ExplSample volume too small for analysis
Code-777.77
ExplAnalyte concentration below detection limit
Code-999.99
ExplData missing or not taken at this time
Code-888.88
ExplSample volume too small for analysis
Code-777.77
ExplAnalyte concentration below detection limit
Code-999.99
ExplData missing or not taken at this time
Code-888.88
ExplSample volume too small for analysis
Code-777.77
ExplAnalyte concentration below detection limit
Code-999.99
ExplData missing or not taken at this time
Code-888.88
ExplSample volume too small for analysis
Code-777.77
ExplAnalyte concentration below detection limit
Code-999.99
ExplData missing or not taken at this time
Code-888.88
ExplSample volume too small for analysis
Code-777.77
ExplAnalyte concentration below detection limit
Code-999.99
ExplData missing or not taken at this time
Code-888.88
ExplSample volume too small for analysis
Code-777.77
ExplAnalyte concentration below detection limit
Code-999.99
ExplData missing or not taken at this time
Code-888.88
ExplSample volume too small for analysis
Code-777.77
ExplAnalyte concentration below detection limit
Code-999.99
ExplData missing or not taken at this time
Code-888.88
ExplSample volume too small for analysis
Code-777.77
ExplAnalyte concentration below detection limit
Code-999.99
ExplData missing or not taken at this time
Code-888.88
ExplSample volume too small for analysis
Code-777.77
ExplAnalyte concentration below detection limit
Code-999.99
ExplData missing or not taken at this time
Code-888.88
ExplSample volume too small for analysis
Code-777.77
ExplAnalyte concentration below detection limit
Accuracy Report:                                              
Accuracy Assessment:                                              
Coverage:                                              
Methods:                                              

Data Package Usage Rights

This information is released under the Creative Commons license - Attribution - CC BY (https://creativecommons.org/licenses/by/4.0/). The consumer of these data ("Data User" herein) is required to cite it appropriately in any publication that results from its use. The Data User should realize that these data may be actively used by others for ongoing research and that coordination may be necessary to prevent duplicate publication. The Data User is urged to contact the authors of these data if any questions about methodology or results occur. Where appropriate, the Data User is encouraged to consider collaboration or co-authorship with the authors. The Data User should realize that misinterpretation of data may occur if used out of context of the original study. While substantial efforts are made to ensure the accuracy of data and associated documentation, complete accuracy of data sets cannot be guaranteed. All data are made available "as is." The Data User should be aware, however, that data are updated periodically and it is the responsibility of the Data User to check for new versions of the data. The data authors and the repository where these data were obtained shall not be liable for damages resulting from any use or misinterpretation of the data. Thank you.

Keywords

By Thesaurus:
LTER Core Research Areainorganic nutrients, organic matter, disturbance patterns
LTER Controlled Vocabularyecosystems, forests, watersheds, aluminum, ammonium, calcium, carbon, chemistry, chloride, dissolved inorganic carbon, dissolved organic carbon, fluoride, lysimeters, magnesium, nitrate, nitrogen, potassium, silica, sodium, soil, soil horizons, soil water, sulfate, water
HBES VocabularyHBR, Hubbard Brook LTER, Hubbard Brook Experimental Forest, Hubbard Brook Ecosystem Study, HBES, HBEF, New Hampshire, NH, White Mountain National Forest
ISO 19115 Topic Categoryenvironment
National Research & Development TaxonomyEcology, Ecosystems, & Environment

Methods and Protocols

These methods, instrumentation and/or protocols apply to all data in this dataset:

Methods and protocols used in the collection of this data package
Description:

LOCATION DESCRIPTION

Tension-free lysimeters are installed in the Oa, Bh and Bs horizons at 3 sites located adjacent to watershed 6 at elevations of 750m (spruce-fir-white beech zone; SFB), 730m (high elevation hardwood zone; HH) and 600m (low elevation hardwood zone; LH). Three replicate lysimeters were installed beneath the Oa and Bh horizons and within the Bs horizon at the HH and LH sites, and two replicate lysimeters were installed in each horizon at the SFB site.

SAMPLING DESIGN

The lysimeters were constructed from either polyethylene funnels filled with acid-washed silica sand that drain into 1-L polyethylene containers or rectangular polyethylene containers filled with acid-washed Teflon beads that drain into 2-L polyethylene bottles. At each site, lysimeters were carefully installed in the wall of excavated soil pits, immediately below the Oa and Bh horizons and within the lower Bs horizon. Soil pits were backfilled to prevent accumulation of water and to eliminate freezing during winter months. Soil solution samples are collected approximately monthly in acid-washed polyethylene bottles and refrigerated at 4 degrees C.

NOTES ON DATA

Between 1984 and 1986 and 1998-present, data are the arithmetic means for samples collected from individual lysimeters. From 1986 through 1998, data are for bulked soil solutions collected from replicate lysimeters. Current detection limits for the Driscoll laboratory: Na (0.015 umol/L), K (0.12 umol/L), Ca (0.030 umol/L), Mg (0.0032 umol/L), Alt (0.0026 umol/L), Alm (1.3 umol/L), Alo (1.3 umol/L), NH4 (0.55 umol/L), H4SiO2 (3 umol/L), Cl (0.55 umol/L), NO3 (0.85 umol/L), SO4 (0.53 umol/L), F (0.097 umol/L), DIC (20 umol/L), DOC (20 umol/L), TN (0.81 umol/L). It is suggested to dataset users to use a value of one half the detection limit when a value for a solute is less than the detection limit. The data is physically located at the Department of Civil and Environmental Engineering, Syracuse University, Syracuse, NY.

PUBLICATIONS DESCRIBING/USING THESE DATA

Dahlgren, R.A., and Driscoll, C.T. 1994. The effects of whole-tree clear-cutting on soil processes at the Hubbard Brook Experimental Forest, New Hampshire, USA. Plant Soil 158:239-262.

Dittman, J.A. Dynamics of Nitrogen and Dissolved Organic Carbon in a Forested Watershed at the Hubbard Brook Experimental Forest. Master of Science, Syracuse University.

Dittman, J.A., Driscoll, C.T., Groffman, P.M., and Fahey, T.J. 2007. Dynamics of nitrogen and dissolved organic carbon at the Hubbard Brook Experimental Forest. Ecology 88(5):1153-1166.

Driscoll, C.T., Fuller, R.D., and Simone, D.M. 1988. Longitudinal variations in trace metal concentrations in a northern hardwood forested ecosystem. J. Environ. Qual. 17(1):101-107.

Fuss, C.B. 2009. Biogeochemical dynamics of oxidized and reduced iron at the Hubbard Brook Experimental Forest. Masters of Science, Syracuse University.

Fuss, C.B., Driscoll, C.T., Johnson, C.E., Petras, R.J., and Fahey, T.J. 2011. Dynamics of Oxidized and Reduced Iron in a Northern Hardwood Forest. Biogeochemistry 104(1-3 (July)):103-119.

Johnson, C.E., Driscoll, C.T., Siccama, T.G., and Likens, G.E. 2000. Element fluxes and landscape position in a northern hardwood forest watershed ecosystem. Ecosystems 3:159-184.

Palmer, S.M. Spatial and temporal patterns in the biogeochemistry of aluminum at the Hubbard Brook Experimental Forest, New Hampshire. Dissertation, Syracuse University.

Palmer, S.M., Driscoll, C.T., and Johnson, C.E. 2004. Long-term trends in soil solution and stream water chemistry at the Hubbard Brook Experimental Forest: relationship with landscape position. Biogeochemistry 68(1):51-70.

People and Organizations

Publishers:
Organization:Environmental Data Initiative
Email Address:
info@environmentaldatainitiative.org
Web Address:
https://environmentaldatainitiative.org
Id:https://ror.org/0330j0z60
Creators:
Individual: Charles T Driscoll
Organization:Syracuse University
Email Address:
ctdrisco@syr.edu
Id:https://orcid.org/0000-0003-2692-2890
Contacts:
Organization:Hubbard Brook Ecosystem Study
Email Address:
hbr-im@lternet.edu

Temporal, Geographic and Taxonomic Coverage

Temporal, Geographic and/or Taxonomic information that applies to all data in this dataset:

Time Period
Begin:
1984-01-28
End:
2020-12-31
Geographic Region:
Description:Hubbard Brook Experimental Forest
Bounding Coordinates:
Northern:  43.959Southern:  43.914
Western:  -71.8062Eastern:  -71.7022
Geographic Region:
Description:Adjacent to HBEF watershed 6.
Bounding Coordinates:
Northern:  43.957001Southern:  43.949928
Western:  -71.743462Eastern:  -71.735649
Sampling Site: 
Description:Location of 750m altitude spruce-fir-white beech zone (SFB) Lysimeters
Site Coordinates:
Longitude (degree): -71.739931Latitude (degree): 43.957423
Sampling Site: 
Description:Location of 600m altitude low-elevation hardwood zone (LH) Lysimeters
Site Coordinates:
Longitude (degree): -71.738842Latitude (degree): 43.950622
Sampling Site: 
Description:Location of 730m altitude high-elevation hardwood zone (HH) Lysimeters
Site Coordinates:
Longitude (degree): -71.741369Latitude (degree): 43.954523

Project

Parent Project Information:

Title:Long-Term Ecological Research at Hubbard Brook Experimental Forest (1988)
Personnel:
Individual: Timothy J Fahey
Organization:Cornell University
Email Address:
tjf5@cornell.edu
Id:https://orcid.org/0000-0003-1283-1162
Role:Principal Investigator
Funding: National Science Foundation (NSF) 8702331
Related Project:
Title:Long-term Ecological Research (LTER) at the Hubbard Brook Experimental Forest (1992)
Personnel:
Individual: Timothy J Fahey
Organization:Cornell University
Email Address:
tjf5@cornell.edu
Id:https://orcid.org/0000-0003-1283-1162
Role:Principal Investigator
Funding: National Science Foundation (NSF) 9211768
Related Project:
Title:LTER: Hubbard Brook Experimental Forest (1998)
Personnel:
Individual: Timothy J Fahey
Organization:Cornell University
Email Address:
tjf5@cornell.edu
Id:https://orcid.org/0000-0003-1283-1162
Role:Principal Investigator
Funding: National Science Foundation (NSF) 9810221
Related Project:
Title:Long-Term Ecological Research (LTER) at Hubbard Brook Experimental Forest (HBR-LTER) (2005)
Personnel:
Individual: Timothy J Fahey
Organization:Cornell University
Email Address:
tjf5@cornell.edu
Id:https://orcid.org/0000-0003-1283-1162
Role:Principal Investigator
Funding: National Science Foundation (NSF) 0423259
Related Project:
Title:Long-Term Ecological Research at Hubbard Brook Experimental Forest (2010)
Personnel:
Individual: Timothy J Fahey
Organization:Cornell University
Email Address:
tjf5@cornell.edu
Id:https://orcid.org/0000-0003-1283-1162
Role:Principal Investigator
Funding: National Science Foundation (NSF) 1114804
Related Project:
Title:LTER: Long Term Ecological Research at the Hubbard Brook Experimental Forest (2016)
Personnel:
Individual: Peter M Groffman
Organization:Cary Institute of Ecosystem Studies
Email Address:
groffmanp@caryinstitute.org
Id:https://orcid.org/0000-0001-8371-6255
Role:Principal Investigator
Funding: National Science Foundation (NSF) 1637685

Maintenance

Maintenance:
Description:ongoing
Frequency:
Other Metadata

Additional Metadata

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